YAMAMOTO, Hideki |
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Faculty, Department/Institute
- Faculty of Environmental and Urban Engineering Department of Chemical, Energy and Environmental Engineering
Academic status (qualification)
- Professor Apr. 1,2004
Position
- 2020/10/1~2024/3/31
- Dean, Division of Research Development 2020/10/1~2024/3/31
- Dean, Division of Community and Business Partnerships 2020/10/1~2024/3/31
Undergraduate Degrees・University
- Kansai University Faculty of EngineeringDepartment of Chemical Engineering 1982 Graduated
Graduate Degrees・University
- Kansai University 1984 Completed
Academic Degrees
- Mar. 1984 Kansai University
- Mar. 1991 Kansai University
Homepage Address, E-mail Address
- Homepage Address:http://www.cheng.kansai-u.ac.jp/Process/Index.html
- E-mail Address:yhideki@kansai-u.ac.jp
Research fields
Research fields | keyword |
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Other | |
Other | |
Other |
Research topics
research topic | New Development of Viscometry Apparatus for Human Blood |
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Study theme state | |
research duration | 1990 ~ 2010 |
Research Programs | |
keyword | |
Research field | |
Research Topics Overview |
research topic | |
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Study theme state | |
research duration | 2003 ~ 2008 |
Research Programs | |
keyword | |
Research field | |
Research Topics Overview |
research topic | |
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Study theme state | |
research duration | 2003 ~ 2008 |
Research Programs | |
keyword | |
Research field | |
Research Topics Overview |
Research Career
- Kansai Univ./Research assisitant
- Kansai Univ./Lecturer
- Kansai Univ./Associate Prof.
- Kansai Univ./Prof.
Awards
- Apr. 1,1998
- Oct. 5,2000
- May 17,1999
- Mar. 31,1984
- Sep. 17,2002
- Jun. 22,2003
- Nov. 10,2005
- May 10,2006
- May 17,2007
- May 21,2008
Academic Associations
所属学会・団体名 | 役職名 (役職在任期間) |
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19950000(2001/), 20020000(2003/), 20010000(2003/), 20050000(2006/) | |
20040000(2005/) |
Intellectual Property Rights
- (Published)
- application number:特願平7-319888 (May 18,1997)
- (May 18,1998)
- (Published)
- application number:特願平11-214539 (Jul. 29,1999)
- (Jul. 29,2000)
- (Acquired)
- application number:特願2002-172222 (May 10,2002)
- (May 10,2003)
- (Published)
- application number:特願2003-043752 (Feb. 21,2003)
- (Feb. 21,2004)
- (Published)
- application number:特願2003-278732 (Jul. 24,2003)
- (Jul. 24,2004)
- (Published)
- application number:特願2003-399014 (Nov. 20,2003)
- (Nov. 20,2004)
- (Published)
- application number:特願2002-172222 (May 10,2002)
- (May 10,2003)
- (Published)
- application number:特願2000-327400 (Oct. 26,2000)
- (Oct. 26,2001)
- application number:特願2009-147506 (Jan. 2009)
- application number:特願2009-147507 (Jan. 2009)
- (Published)
- application number:特願2000-216113 (Jul. 17,2000)
- application number:2001-96104 (Apr. 10,2001)
- (Published)
- application number:特願2000-268184 (Sep. 5,2000)
- application number:2002-79035 (Mar. 19,2002)
- (Published)
- application number:特願2000-341280 (Nov. 9,2000)
- application number:2002-143891 (May 21,2002)
- (Published)
- application number:特願2003-011036 (Jan. 20,2003)
- application number:2004-223321 (Aug. 12,2004)
- (Published)
- application number:特願2003-141951 (May 20,2003)
- application number:2004-345876 (Dec. 9,2004)
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- application number:特願2003-163360 (Jun. 9,2003)
- application number:2004-066227 (Mar. 4,2004)
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- application number:特願2003-289144 (Aug. 7,2003)
- application number:2005-054148 (Mar. 3,2005)
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- application number:特願2004-146319 (May 17,2004)
- application number:2005-324164 (Nov. 24,2005)
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- application number:特願2004-350135 (Dec. 2,2004)
- application number:2006-160534 (Jun. 22,2006)
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- application number:特願2004-349380 (Dec. 2,2004)
- application number:2006-158986 (Jun. 22,2006)
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- application number:特願2005-011093 (Jan. 19,2005)
- application number:2006-199604 (Aug. 3,2006)
- (Published)
- application number:特願2006-191039 (Jul. 12,2006)
- application number:2008-019191 (Jan. 31,2008)
- (Published)
- application number:特願2006-084717 (Mar. 27,2006)
- application number:2007-254254 (Oct. 4,2007)
- (Published)
- application number:特願2006-108191 (Apr. 11,2006)
- application number:2007-275830 (Oct. 25,2007)
- (Published)
- application number:特願2006-112092 (Apr. 14,2006)
- application number:2007-282543 (Nov. 1,2007)
- (Published)
- application number:特願2008-050409 (Feb. 29,2008)
- application number:2009-22605 (Oct. 8,2009)
- (Published)
- application number:特願2008-125996 (May 13,2008)
- application number:2009-274893 (Nov. 26,2009)
- (Published)
- application number:特願2004-344201 (Nov. 29,2004)
- application number:2006-151744 (Jun. 15,2006)
- (Published)
- application number:特願2005-022513 (Jan. 31,2005)
- application number:2006-208260 (Aug. 10,2006)
- (Published)
- application number:特願2005-319114 (Nov. 2,2005)
- application number:2007-127468 (May 24,2007)
- (Published)
- application number:特願2005-319118 (Nov. 2,2005)
- application number:2007-127469 (May 24,2007)
- (Published)
- application number:特願2005-319127 (Nov. 2,2005)
- application number:2007-127470 (May 24,2007)
- (Published)
- application number:特願2005-319130 (Nov. 2,2005)
- application number:2007-127471 (May 24,2007)
- (Published)
- application number:特願2008-139606 (May 28,2008)
- application number:2009-286867 (Dec. 10,2009)
- (Published)
- application number:特願2005-73264 (Mar. 15,2005)
- application number:2006-256977 (Sep. 28,2006)
- (Published)
- application number:特願2004-283770 (Sep. 29,2004)
- application number:2006-96846 (Apr. 13,2006)
- (Published)
- application number:特願2003-285503 (Aug. 4,2003)
- application number:2005-052724 (Mar. 3,2005)
- (Published)
- application number:特願2009-019806 (Jan. 30,2009)
- application number:2010-172845 (Aug. 12,2010)
- (Published)
- application number:特願2009-033449 (Feb. 17,2009)
- application number:2009-226205 (Oct. 8,2009)
- (Published)
- application number:特願2009-047649 (Mar. 2,2009)
- application number:2010-202433 (Sep. 16,2010)
- (Published)
- application number:特願2009-296759 (Dec. 28,2009)
- application number:2011-136854 (Jul. 14,2011)
Joint Projects/Commissioned Projects
2005 - 2006 Domestic Joint Research
2005 - 2006 Domestic Joint Research
2005 - 2006 From contract research companies
2005 - 2006 From contract research companies
2002 - 2003 From contract research companies
2004
2000 - 2001
2006 - 2007 Domestic Joint Research
Research Publications
Papers2022/9~
Papers2022~
Papers2022~
PapersIn refereedYang Ren;Yen-Tsz Bieh;Celine H. Chen;Chang-Yen Hsu;Yuki Kato;Hideki Yamamoto;Chia-Kuang Tsung;Kevin C.-W. Wu2021/9~
PapersIn refereedMorimoto, M;Sato, T;Fukatsu, N;Morita, T;Yamamoto, H;Tanaka, R2021/5~
PapersIn refereedTakashi Suzuki;Hiroyuki Takao;Tomoaki Suzuki;Shunsuke Hataoka;Tomonobu Kodama;Ken Aoki;Katharina Otani;Toshihiro Ishibashi;Hideki Yamamoto;Yuichi Murayama;Makoto Yamamoto2021/4~
PapersIn refereedAcademic JournalCo-authorTakumi Fujii;Len Ito;Shuhei Watanabe;Hideki Yamamoto2021/1~
PapersIn refereedLen,Ito;Takumi,Fujii;Shuhei,Watanabe;Hideki,Yamamoto2021/1~
PapersIn refereedHideki Yamamoto;Takafumi Yabuta;Yusuke Negi;Daiki Horikawa;Kimito Kawamura;Eiji Tamura;Katsuhiro Tanaka;Fujimaro Ishida2020/9~
PapersIn refereedYuki Kato;Takuya Osawa;Mototsugu Yoshihara;Hiroaki Fujii;Shinichi Tsutsumi;Hideki Yamamoto2020/5~
Chapter or Section2020/3~
Chapter or Section2020~
PapersKobayashi, Yumi;Tokishita, Sonoko;Yamamoto, Hideki2020~
PapersIn refereed2020~
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Academic presentation2019/12~
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PapersIn refereed2019/1~
PapersIn refereedInternational coauthorship2019~
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PapersIn refereed2019~
PapersIn refereed5(2019)e028332019~
PapersIn refereed2019~
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PapersIn refereedVol.98 No.6 Page.665-6692019~
PapersIn refereed2019~
PapersIn refereedCo-author2019~
2019~
Academic presentation2018/10~
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Academic presentation2018/5~
PapersIn refereedCo-author2018~
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Academic presentationCo-author2014/12/9~
PapersIn refereedCo-author2014/12~
Academic presentationCo-author2014/11/26~
PapersIn refereedAcademic JournalCo-author2014/11~
PapersIn refereedAcademic JournalCo-author2014/10~
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PapersIn refereedAcademic JournalCo-author2014/9~
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International academic conferenceCo-author2014/7/15~2014/7/18
PapersIn refereedCo-author2014/7~
Academic presentation2014/3/18~2014/3/20
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Academic presentationCo-author2014/3/18~2014/3/20
Academic presentationCo-author2014/1/23~2014/1/24
Academic presentationSingle-AuthorYAMAMOTO,Hideki2014/1/23~2014/1/24
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PapersIn refereedAcademic JournalCo-author2014/1~
Academic presentationSingle-AuthorYAMAMOTO,Hideki2013/11/6~
International academic conference2013/10/20~2013/10/23
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Academic presentationCo-author2013/9/16~2013/9/18
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Academic presentationCo-author2013/9/16~2013/9/18
PapersIn refereedAcademic JournalCo-author2013/9~
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International academic conferenceCo-author2013/7/9~2013/7/12
International academic conferenceCo-authorYAMAMOTO,Hideki2013/6/9~2013/6/11
Academic presentationCo-author2013/6/6~2013/6/8
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PapersIn refereedAcademic JournalCo-authorYAMAMOTO,Hideki2013/5~
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LectureSingle-AuthorYAMAMOTO,Hideki2012/10/9~
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Academic presentationCo-authorYAMAMOTO,Hideki2012/6/1~2012/6/2
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Academic presentationCo-authorYAMAMOTO,HidekiVol.16th, p.180-1832012/1/20~
LectureCo-authorYAMAMOTO,Hideki2011/12/9~
PapersIn refereedCo-authorYAMAMOTO,Hideki2011/11/30~
CommentaryUnrefereedIn-house publicationCo-authorYAMAMOTO,Hideki2011/11/22~
Academic presentationCo-authorYAMAMOTO,Hideki2011/11~
LectureSingle-AuthorYAMAMOTO,Hideki2011/11~
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Academic presentationCo-authorYAMAMOTO,Hideki2011/9/14~2011/9/16
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CommentaryYAMAMOTO,Hideki2011/3/25~
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PapersIn refereedAcademic JournalCo-authorYAMAMOTO,Hideki2010/12~
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CommentaryYAMAMOTO,Hideki2010/9~
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PatentsYAMAMOTO,Hideki;;;YAMAMOTO Hideki2005/3/15~
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PapersIn refereedCo-authorYAMAMOTO,Hideki;;;YAMAMOTO Hideki2005~
PapersSeparation of Acids from Waste Solutions Containing Phosphoric, Nitric and Acetic Acids with Solvent ExtractionIn refereedCo-authorJ.Shibata;M.Morikawa;N.Murayama;H.YamamotoSolvent Extraction Research and Development, JapanVol.12 pp.177-1882005~
PapersPreparation of Sm (III) and Co (II) Composite Oxalates by Crystallization-Stripping MethodIn refereedCo-authorJ.Shibata;S.Matsumoto;N.Murayama;H.YamamotoMetallurgical Review of MMIJVol.18, No.1 pp.49-602005~
PapersIn refereedCo-authorYAMAMOTO,Hideki;;;YAMAMOTO Hideki2005~
PapersIn refereedCo-authorYAMAMOTO Hideki2005~
PapersHydrothermal Synthesis of Pottasium-type Zeolite from Coal Fly Ash and Evaluation of its Physical PropertyUnrefereedCo-authorT.Takahashi;N.Murayama;H.Yamamoto;J.ShibataTechnology Reports of Kansai UniversityNo.47 pp.11-202005~
PapersRegeneration of Tetramethyl Ammonium Hydroxide Using Ion Exchange ResinUnrefereedCo-authorT.Yanase;N.Murayama;H.Yamamoto;J.ShibataTechnology Reports of Kansai UniversityNo.47 pp.21-302005~
Static and Dynamic Synergistic Effects for Ni(II) Extraction and the Application to Waste Solution Containing Ni(II)In refereedCo-authorJ.Shibata;Y.Motoda;N.Murayama;H.Yamamoto2005 TMS Annual Meeting, EPD Congress 2005, Symposium on Metallurgical Technology for Waste Minimization, San Franciscopp.845-8512005~
Development of Recovery Process of Tetramethyl Ammonium Hydroxide from Waste SolutionIn refereedCo-authorJ.Shibata;T.Yanase;N.murayama;H.Yamamoto2005 TMS Annual Meeting, EPD Congress 2005, Symposium on Metallurgical Technology for Waste Minimization, San Franciscopp.907-9162005~
Extraction Properties of Flavonoides and Salt from Bean Cake Discarded in Soy Sauce Manufacturing ProcessIn refereedCo-authorH.Yamamoto;F.Takeuchi;C.Nagano;N.Murayama;J.Shibata88th Canadian Chemistry Conference and Exhibition, Canada, Junepp.253-2592005~
Extraction of Polyphenols in Hop Waste Discharged from a Beer BreweryIn refereedCo-authorH.Yamamoto;C.Nagano;F.Takeuchi;N.Murayama;J.Shibata88th Canadian Chemistry Conference and Exhibition, Canada, Junepp.351-3562005~
Dispersion Phenomena of Metal Oxide Particles in Various SolventsIn refereedCo-authorJ.Shibata;S.Matsumoto;N.Murayama;H.Yamamoto7th World Congress of Chemical Engineering, July, GlasgowO32-001 pp.1-92005~
Removal of Toxic Metal Ions with Functional Inorganic Materials Produced from Wastes in Non-ferrous Metal IndustryIn refereedCo-authorJ.Shibata;N.Murayama;K.Sakai;H.Yamamoto7th World Congress of Chemical Engineering, July, GlasgowP40-009 pp.1-72005~
Extraction Properties of Flabonoids in Bean Cake Disposed frpm Soy Sauce Manufacturing ProcessIn refereedCo-authorH.Yamamoto;F.Takeuchi;C.Nagano;A.Sasaki;J.Shibata7th International Conference of Separation Science and Technology between Korea and Japan, August, KoreaEX6 pp.1-72005~
Adsorption of Toxic Materials onto Polymer Gel Synthesized from Modified PVAIn refereedCo-authorH.Yamamoto;M.Yamatsuka;K.Okamoto;J.Shibata7th International Conference of Separation Science and Technology between Korea and Japan, August, KoreaAD pp.1-72005~
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PatentsYAMAMOTO,Hideki;;YAMAMOTO Hideki2004/11/29~
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PapersIn refereedCo-authorYAMAMOTO,Hideki;YAMAMOTO Hideki2004~
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PapersSynergistic Effect of Ni Extraction and the Application for Waste Solution in Ni Non-electric PlatingUnrefereedCo-authorN.Yoshikawa;M.Yajima;N.Murayama;H.Yamamoto;J.ShibataTechnology Reports of Kansai UniversityNo.46 pp.11-192004~
PapersUnrefereedCo-authorYAMAMOTO Hideki2004~
Removal Treatment of Harmful Materials in Waste Water UsingTemperature-sensitive Polymer GelIn refereedCo-authorH.Yamamoto;A.Kushida;N.Heyamoto;Y.Takami;N.Murayama;J.Shibata2004 TMS Annual Meeting, EPD Congress 2004, Symposium on Solid and Aqueous Wastes from Non-Ferrous Metal Industry, Charlottepp.641-6482004~
Production of Functional Inorganic Materials, AlPO4-5, from Wastes in Aluminum Regeneration IndustryIn refereedCo-authorJ.Shibata;N.Murayama;H.Yamamoto2004 TMS Annual Meeting, EPD Congress 2004, Symposium on Solid and Aqueous Wastes from Non-Ferrous Metal Industry, Charlottepp.659-6632004~
Synthesis of Hydrotalcite from the Wastes Discharged in Aluminum Regeneration ProcessIn refereedCo-authorN.Murayama;M.Tanabe;H.Yamamoto;J.Shibata2004 TMS Annual Meeting, EPD Congress 2004, Symposium on Solid and Aqueous Wastes from Non-Ferrous Metal Industry, Charlottepp.665-6692004~
Development of Separation Process of Tetramethyl Ammonium Hydroxide Using Ion Exchange ResinIn refereedCo-authorJ.Shibata;T.Yanase;N.Murayama;H.YamamotoCHISA2004, CD-ROM of Full Texts, Prahap. D42004~
Separation and Recovery of Acids from Waste Acid Mixture Containing Phosphoric, Nitric and Acetic Acids with Solvent ExtractionIn refereedCo-authorJ.Shibata;K.Ohata;N.Murayama;H.YamamotoCHISA2004, CD-ROM of Full Texts, Prahap. D62004~
Harmless Disposal of Alternative Refrigerant (C2H2F4) Using Chemical Reaction with Metal Oxides and Calcium CarbideIn refereedCo-authorH.Yamamoto;T.Kinoshita;T.Matsui;N.Murayama;J.Shibata87th Canadian Chemistry Conference and Exhibition, Londonpp.965-9662004~
Synthesis of Physical Properties of Zeolite from Coal Ash and its Application for Environmental ProtectionIn refereedCo-authorJ.Shibata;N.Murayama;M.Yajima;H.YamamotoISIEM 2004, Amsterdamp.52004~
Hydrothermal Synthesis of AlPO4-5 Type Zeolite Materials by Using Aluminum Dross as a Raw MaterialIn refereedCo-authorN.Murayama;N.Okajima;H.Yamamoto;J.ShibataISIEM 2004, Amsterdamp.62004~
Hydrothermal Synthesis of Functional Inorganic Materials from the Waste in Non-ferrous Metal IndustryIn refereedCo-authorJ.Shibata;N.Murayama;H.YamamotoPressure Hydrometallurgy 2004, Canadapp.795-8052004~
Regeneration process of Tetramethyl Ammonium Hydroxide with Cation and Anion Exchange ResinsIn refereedCo-authorJ.Shibata;S.Park;T.Yanase;N.Murayama;H.YamamotoInternational Symposium on Green Technology for Resources and Materials Recycling, Seoulpp.340-3482004~
Theoretical Analysis for Recovering Indium from ITO ResidueIn refereedCo-authorJ.Shibata;S.Park;S.Matsumoto;N.Murayama;H.YamamotoInternational Symposium on Green Technology for Resources and Materials Recycling, Seoulpp.369-3722004~
Synthesis of Hydrotalcite from Aluminum Dross and its Anion Exchange PropertiesIn refereedCo-authorJ.Shibata;N.Murayama;K.Sakai;H.YamamotoThe 2nd Korea/Japan International Symposium on Resources Recycling and Materials Science, Danyangpp.95-1022004~
Application of Zeolite Derived from Coal Fly Ash for Environmental ProtectionIn refereedCo-authorN.Murayama;M.Yajima;H.Yamamoto;J.ShibataThe 2nd Korea/Japan International Symposium on Resources Recycling and Materials Science, Danyangpp.159-1672004~
Harmless Disposal of Global Warming Gases (HFC-134a) Using Chemical ReactionIn refereedCo-authorH.Yamamoto;T.Takahashi;T.Matsui;A.Kushida;N.Murayama;J.ShibataThe 2nd Korea/Japan International Symposium on Resources Recycling and Material Sciences, Danyangpp.168-1782004~
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PatentsYAMAMOTO Hideki2003/11/20~
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CommentaryCo-authorYAMAMOTO,Hideki2003/1~
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PapersSimultaneous Removal and its Mechanism for NH4+ and PO43- in Solution Using Zeolite Synthesized from Coal Fly AshIn refereedCo-authorN.Murayama;S.Yoshida;Y.Takami;H.Yamamoto;J.ShibataSeparation Science and TechnologyVol.38, No.1 pp.113-1292003~
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PapersVolmetric Change and Surface Properties of Temperature-sensitive Polyvinylalcohol HydrogelIn refereedCo-authorH.Yamamoto;N.Heyamoto;T.Matsui;N.Murayama;J.ShibataInternational Journal of Thermophysics, Special IssueVol.24, No.5 pp.1385-13942003~
PapersRemoval of Harmful Organic Compounds in Water Using Temperature-sensitive Polymer GelIn refereedCo-authorH.Yamamoto;N.Heyamoto;J.ShibataJournal of Chemical Engineering of JapanVol.29, No.3 pp.506-5102003~
PapersIn refereedCo-authorYAMAMOTO,Hideki;;;;;;YAMAMOTO Hideki2003~
PapersNovel Treatment Process of Harmful Organic Materials in Waste Water Using Temperature-sensitive Gel Synthesized from PVAIn refereedCo-authorH.Yamamoto;A.Kushida;N.Heyamoto;Y.Takami;N.Murayama;J.ShibataMaterials TransactionsVol.44, No.12 pp.2436-24402003~
PapersReaction, Mechanism and Application of Various Zeolite Syntheses from Coal Fly AshIn refereedCo-authorN.Murayama;M.Tanabe;H.Yamamoto;J. ShibataMaterials TransactionsVol.44, No.12 pp.2475-24802003~
PapersHydrothermal Synthesis of Potassium-chabazite from Coal Fly Ash TechnologyUnrefereedCo-authorM.Tanabe;S.Yoshida;N.Murayama;H.Yamamoto;J.ShibataReports of Kansai UniversityNo.45 pp.1-82003~
Recovery of Pd from Waste Solution Containing Pd Catalyst Used in Copper Non-electric PlatingIn refereedCo-authorJ.Shibata;M.Kobayashi;H.Yamamoto;N.Murayama2003 TMS Annual Meeting, EPD Congress 2003, San Diegopp.517-5232003~
Fundamental Study for Recovery of Ni2+ from Waste Solution in Ni2+ Non-electric PlatingIn refereedCo-authorJ.Shibata;N.Yoshikawa;N.Murayama;H.Yamamoto2003 TMS Annual Meeting, EPD Congress 2003, San Diegopp.495-5032003~
Cation Exchange Properties of Zeolites Obtained from Coal Fly Ash by Alkali Hydrothermal TreatmentIn refereedCo-authorN.Murayama;H.Yamamoto;J.Shibata2003 TMS Annual Meeting, Yazawa International symposium, San Diegopp.65-752003~
Disposal Treatment of Alternative CFC Gas (C2H2F4) Using Chemical Reaction with Metal CompoundsIn refereedCo-authorH.Yamamoto;A.Kushida;N.Murayama;J.Shibata2003 TMS Annual Meeting, Yazawa International symposium, San Diegopp.1105-11102003~
Recovery of Phosphoric Acid in Waste Acid Mixture Discharged from the Liquid Crystal Industry by Solvent ExtractionIn refereedCo-authorJ.Shibata;M.Morikawa;N.Yoshikawa;N.Murayama;H.YamamotoHydro 2003, Vancouverpp.853-8602003~
Hydrothermal Synthesis of Potassium Type Zeolite from Coal Fly Ash and the Physical PropertyIn refereedCo-authorN.Murayama;M.Tanabe;S.Yoshida;H.Yamamoto;J.ShibataCOM 2003 The 42nd Conference of Metallurgist, Ecomaterials and Ecoprocesses Syposium, Vancouverpp. 207-2152003~
Zeolite Synthesis from Coal Fly Ash and its Application for Environmental ProtectionIn refereedCo-authorN.Murayama;H.Yamamoto;J.ShibataThe Japan/Korea International Symposium on Resources Recycling and Materials Science, Osakapp.167-1722003~
Development of Removal Process for Harmful Organic Materials in Waste Water using Temperature-sensitive Polymer GelIn refereedCo-authorH.Yamamoto;A.Kushida;N.Murayama;J.ShibataThe Japan/Korea International Symposium on Resources Recycling and Materials, Osakapp.261-2712003~
Hydrothermal Synthesis and Reaction Mechanism of Zeolite from Coal Fly Ash in the Presence of Various Alkali SourcesIn refereedCo-authorJ.Shibata;H.Yamamoto;N.MurayamaXXII International Mineral Processing Congress, Cape townp.3332003~
Extraction and Recovery of Phosphoric Acid in Waste Acid Mixture Discharged from Liquid Crystal IndustryIn refereedCo-authorJ.Shibata;M.Morikawa;N.Murayama;H.YamamotoThe 7th International Symposium on East Asian Resources Recycling Technology, Tainanpp.59-622003~
Synthesis of Potassium Chabazite from Coal Fly Ash and the Cation Exchange PropertiesIn refereedCo-authorN.Murayama;S.Yoshida;H.Yamamoto;J.ShibataThe 7th International Symposium on East Asian Resources Recycling Technology, Tainanpp.187-1902003~
Harmless Disposal of Refrigerant C2H2F4 Using Chemical Reaction with Metal CompoundsIn refereedCo-authorH.Yamamoto;T.Matsui;T.Kinoshita;N.Murayama;J.ShibataThe 7th International Symposium on East Asian Resources Recycling Technology, Tainanpp.229-2322003~
Hydrothermal Synthesis of AlPO4-5 from Aluminum Dross and the Physical PropertiesIn refereedCo-authorN.Okajima;N.Murayama;H.Yamamoto;J.ShibataThe 7th International Symposium on East Asian Resources Recycling Technology, Tainanpp.415-4182003~
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PatentsYAMAMOTO,Hideki;YAMAMOTO Hideki2002/11/11~
PatentsYAMAMOTO,Hideki;YAMAMOTO Hideki2002/5/10~
PapersPrediction of Salt Effect on Vapor-Liquid Equilibria of Alcohol+Alcohol and Alcohol+Water Binary
MixtureYAMAMOTO HidekiHigh Temperature and High PressureVol.34, pp.81-892002/1/20~
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PapersDispersion and Flocculation Behaivior of Rare Earth Oxide Powders in Organic SolventIn refereedAcademic JournalCo-authorYAMAMOTO,Hideki;;YAMAMOTO Hidekisolubility parameter;organic solvent;dispersion;flocculation;rare earth oxide2002~
PapersFormation Behavior of Potassium-Chabazite from Coal Fly AshIn refereedAcademic JournalCo-authorYAMAMOTO HidekiRecycle;Ion Exchange;Alkali Hydrothermal Synthesis;Zeolite;Coal Fly Ash2002~
PapersMechanism of zeolite synthesis from coal fly ash by alkali hydrothermal reactionIn refereedAcademic JournalCo-authorYAMAMOTO Hidekireaction mechanism;hydrothermal synthesis;coal fly ash;zeoliteInt.J.Miner.Process64(2002)1-172002~
PapersPreparation of Ag-NiO Composite Powders by Spray Pyrolysis from Ag and Ni Loading Versatic Acid 10In refereedAcademic JournalCo-authorYAMAMOTO HidekiNickel;Silver;Nitrate;Composite Powders;Spray Thermal Decomposition;Solvent Extraction2002~
PapersSeparation and Recovery of Acid from Waste Acid Mixture in Silicon Wafer Manufacturing IndustryIn refereedAcademic JournalCo-authorYAMAMOTO Hidekizero emission;etching solution;waste acid;silicon wafer;solvent extraction2002~
PapersDevelopment of Production Process of Charcoal Bricks from Spent GrainIn refereedAcademic JournalCo-authorYAMAMOTO Hidekicharcoal bricks;thermal conversion;spent grain2002~
PapersDispersion and Flocculation Behavior of Fine Metal Oxide Particles in Various SolventsIn refereedAcademic JournalCo-authorYAMAMOTO HidekiKONA Powder and Particle2002~
PapersZeolite Synthesis from Coal Fly Ash by Hydrothermal Reaction Using Various Alkali SourcesIn refereedCo-authorN.Murayama;H.Yamamoto;J.ShibataJournal of Chemical Technology and Biotechnology, Special IssueVo.77, No.3 pp.280-2862002~
PapersMechanism of Zeolite Synthesis from Coal Fly Ash by Alkali Hydrothermal ReactionIn refereedCo-authorN.Murayama;H.Yamamoto;J.ShibataInternational Journal of Mineral ProcessingVol.64, No.1 pp.1-172002~
PapersIn refereedCo-authorYAMAMOTO,Hideki;;;YAMAMOTO Hideki2002~
PapersCrystallization-stripping of Sm(III) and Co(II) as Composite Oxalates and their Physical PropertiesUnrefereedCo-authorT.Kumano;K.Sasabe;N.Murayama;H.Yamamoto;J.ShibataTechnology Reports of Kansai UniversityNo.44 pp.67-762002~
PapersUnrefereedCo-authorYAMAMOTO,Hideki;YAMAMOTO Hideki2002~
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Environmentally Friendly Usage Method of Zeolite Derived from Coal Fly AshIn refereedCo-authorJ.Shibata;N.Murayama;H.YamamotoEPD Congress 2002, 2002 TMS Annual Meeting, Symposium on Fly Ash, USApp.241-2492002~
Simultaneous Removal Technology of N and P Components in Aqueous Solution by Ca Type Zeolite Synthesized from Coal Fly AshIn refereedCo-authorH.Yamamoto;N.Murayama;J.ShibataEPD Congress 2002, 2002 TMS Annual Meeting, Symposium on Fly Ash, USApp.269-2782002~
Hydrothermal Synthesis and its Reaction Mechanism of K Type Zeolite from Coal Fly Ash Using KOH SolutionIn refereedCo-authorN.Murayama;H.Yamamoto;J.ShibataEPD Congress 2002,2002 TMS Annual Meeting, Symposium on Fly Ash,USApp.261-2682002~
Application of Solvent Extraction to the Production of Multi-component Composite PowderIn refereedCo-authorJ.Shibata;H.YamamotoInternational Solvent Extraction Conference 2002, South AfricaVol. 1 pp.543-5472002~
Separation and Recovery of Wasted Acids by Solvent Extraction,
TMS Fall 2002 Extraction and Processing Division, Meeting on Recycling and WasteIn refereedCo-authorJ.Shibata;H.Yamamoto;N.MurayamaTreatment in Mineral and Metal Processing, Swedenpp.755-7622002~
Volume Change and Structure Properties of Temperature-sensitive Polyvinylalcohol
(PVA) HhydrogelIn refereedCo-authorH.Yamamoto;N.Heyamoto;T.Matsui;N.Murayama;J.ShibataETCP2002, Londonpp.290-2922002~
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PatentsYAMAMOTO,Hideki;;;YAMAMOTO Hideki2001/9/20~
PapersBehavior of Crystallization Stripping of Ag Carbonate and Ag-Ni Composite Carbonate and Their Physicochemical Properties -Studies on production of composite powders with crystallization stripping(2nd Report)-In refereedAcademic JournalCo-authorYAMAMOTO HidekiNickel;Silver;Composite Powder;Crystallization Stripping;Solvent Extraction2001~
PapersPhysical Property and Burning Property of Spent Grain CharcoalIn refereedAcademic JournalCo-authorYAMAMOTO HidekiPhysical Property;Burning Property;Combustion;Charcoal;Sawdust;Spent Grain2001~
PapersSm(Ⅲ)-Co(Ⅱ)複合シュウ酸塩の晶析剥離特性とその物資-晶析剥離法による複合粉体の製造に関する研究(第1報)-In refereedAcademic JournalCo-authorYAMAMOTO HidekiCo;Sm;Composite powder;Oxalate;Solvent Extraction;Crystallizing-stripping2001~
PapersCation-Exchange Properties of Zeolite Synthesized from Coal Fly Ash by Hydrothermal ReactionIn refereedAcademic JournalCo-authorYAMAMOTO HidekiIon-exchange Capacity;Hydration Ionic Radius;Hydrothermal Reaction;Cation Exchange;Coal Fly Ash2001~
PapersEvaluation of Coal Fly Ash and Incineration Ash as Raw Material for Zeolite SynthesisIn refereedAcademic JournalCo-authorYAMAMOTO HidekiRecycle;Hydrothermal Synthesis;Zeolite;Incineration Ash;Coal Fly Ash2001~
PapersDispersion and Flocculation Behavior of Metal Oxide Powders in Organic SolventIn refereedAcademic JournalCo-authorYAMAMOTO,Hideki;;YAMAMOTO Hidekidielectric constant;solubility parameter;organic solvent;dispersion;flocculation;metal Oxide2001~
PapersMicroscopic Studies of Internal Structure of Ag-NiO Composite Powder Prepared by Spray Pyrolysis
-Preparation of Ag-NiO composite powders by spray pyrolysis(3rd Report)-In refereedAcademic JournalCo-authorYAMAMOTO HidekiMicroscopic Analysis;Crystallite;Nickel;Silver;Composite Powders;Spray Pyrolysis2001~
PapersIn refereedCo-authorYAMAMOTO,Hideki;;YAMAMOTO Hideki2001~
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PapersFlocculation Behavior of TiO2 in Aqueous Solution Containing Hydrophilic PolymersUnrefereedCo-authorK.Fujii;H.Yamamoto;J.ShibataTechnology Report of Kansai UniversityNo.43 pp.119-1292001~
PapersUnrefereedCo-authorYAMAMOTO,Hideki;;YAMAMOTO Hideki2001~
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Application of Solvent Extraction to the Production of Two Component Composite PowdersIn refereedCo-authorJ.Shibata;H.Yamamoto2001 EPD Congress, 2001 TMS Annual Meeting, Louisianapp.657-6632001~
Zeolite Synthesis from Coal Fly Ash by Hydrothermal Reaction Using Various Alkali SourcesIn refereedCo-authorN.Murayama;H.Yamamoto;J.ShibataMORELLA 2001, International Workshop on Novel Products from Combustion Residues, Spainpp.137-1422001~
Application for Solvent Extraction to the Treatment of Industrial WasteIn refereedCo-authorJ.Shibata;H.Yamamoto6th International Symposium on East Asian Resources Recycling Technology, Koreapp.259-2632001~
Treatment of Waste Dry Etching Gas in Semiconductor Manufacturing ProcessIn refereedCo-authorH.Yamamoto;T.Kawahara;J.Shibata6th International Symposium on East Asian Resources Recycling Technology, Koreapp.711-7142001~
Dispersion and Flocculation Behavior of Metal Oxide in Organic SolventIn refereedCo-authorK.Fujii;H.Yamamoto;J.Shibata6th International Symposium on East Asian Resources Recycling Technology, Koreapp.353-3562001~
Suitability of Coal Fly Ash and Incineration Ashes as Raw Materials for Zeolite SynthesisIn refereedCo-authorN.Murayama;Y.Yamakawa;K.Ogawa;Y.Takami;H.Yamamoto;J.Shibata6th International Symposium on East Asian Resources Recycling Technology, Koreapp.616-6202001~
Application of Solvent Extraction to the Production of Composite Metal Oxide PowderIn refereedCo-authorJ.Shibata;H.Yamamoto4th Paciffic Rim International Conference on Advanced Materials and Processing, USApp.2279-22822001~
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BookReaction Mechanism of Zeolite Synthesis from Coal Fly AshCo-authorYAMAMOTO,Hideki;;;YAMAMOTO HidekiShigen-to-Sozai2000~In other to clarify the reaction mechanism of zeolite synthesis from coal fly ash, zeolite was synthesized by using various alkali solutions. Alkali solutions of single and two component systems of NaOH, Na2CO3 and KOH were used for zeolite synthesis. The surface structure of zeolites obtained under verious conditions was evaluated, and the role of alkali solution on zeolite synthesis was investigated.
In the case of single component alkali solutions, zeolite P was produced from only NaOH solution under an ordinary synthesis condition(393 K reaction temperature, 3 hrs. reaction time and 2 mol/dm3 alkali concentration). It was confirmed that chabazite was synthesized by extending of reaction time in KOH solution. In the case of two component alkali solutions, zeolite was produced at the particular mixing composition. As the results, it was found that OH-ion in alkali solution contributed to the dissolution of coal fly ash, and Na+ ion contributed to the crystallization of zeolite. Also, it was confirmed that the important factor to fasten the reaction rate of zeolite synthesis was Na+ ion in alkali solution. In this study, the reaction mechanism of zeolite synthesis from coal fly ash was clarified.
BookWater Purification Property of Zeolite Synthesized from Coal Fly AshCo-authorYAMAMOTO,Hideki;;;YAMAMOTO HidekiShigen-to-Sozai2000~Cation exchange properties of K and Ca type zeolites were investigated using Na type zeolite synthesized from coal fly ash under hydrothermal conditions. The caion exchange capacity(CEC)of the Na type zeolite was about 300 meq/100 g. The cation exchange amount of Ca type zeolite substituted from Na type zeolite was measured for NH┏ss3┓+┏/ss3┓┏ss4┓4┏/ss4┓ and PO┏ss3┓3-┏/ss3┓┏ss4┓4┏/ss4┓ in order to evaluate the efficiency of zeolite as a water purification agent.
Na type zeolite was exchanged with K+ and Ca2+ in the pH region of around 7. The exchanged amount of K+ did not depend on the kinds of anion in the aqueous solution, while the amount of exchanged Ca2+ depended on them. It was found that the substitution percentage from Na+ to Ca2+ reached to about 90% of CEC, if the cation exchange operation was repeated.
In the cation exchange reaction for NH┏ss3┓+┏/ss3┓┏ss4┓4┏/ss4┓, Na type zeolite exchanged much more NH┏ss3┓+┏/ss3┓┏ss4┓4┏/ss4┓ than Ca type zeolite. In the case of PO┏ss3┓3-┏/ss3┓┏ss4┓4┏/ss4┓, Ca type zeolite removed PO┏ss3┓3-┏/ss3┓┏ss4┓4┏/ss4┓ from the aqueous solution by the precipitation reaction between Ca2+ released from the zeolite and PO┏ss3┓3-┏/ss3┓┏ss4┓4┏/ss4┓ in the solution. On the other hand, Na type zeolite could not remove PO┏ss3┓3-┏/ss3┓┏ss4┓4┏/ss4┓ from the mixed aqueous solution. In the adsorption behaviors of NH┏ss3┓+┏/ss3┓┏ss4┓4┏/ss4┓ and PO┏ss3┓3-┏/ss3┓┏ss4┓4┏/ss4┓ from the mixed aqueous solution with Ca type zeolite, approximately 90% and 46% removal was accomplished for NH┏ss3┓+┏/ss3┓┏ss4┓4┏/ss4┓ and PO┏ss3┓3-┏/ss3┓┏ss4┓4┏/ss4┓, respectively. The ion of PO┏ss3┓3-┏/ss3┓┏ss4┓4┏/ss4┓ was precipitated quantitatively with Ca2+ relased from Ca type zeolite in the solution.
BookExtraction of Pd(II)with Solvating Type Extractant, EHO, and Its StrippingCo-authorYAMAMOTO,Hideki;;;;YAMAMOTO HidekiSHIGEN-TO-SOZAI2000~The precious metal has a long history of usage not only as jewelry but as the industrial materials such as catalysis, parts of electrical products and dental filling. The precious metal is extremely expensive because of the small amount of the deposit. The supply of the precious metal from recycling is more desirable than that from the ore deposit. As the method of recovery of the precious metal, precipitation-crystallization has been emploved, but a lot of process steps are needed to obtain the recovery with high purity and high yield. In stead of the method mentioned above, solvent extraction with 2-ethylhexanal oxime(EHO), which is known as the selective extracant for Cu(Ⅱ), Ni(Ⅱ)and Pd(Ⅱ), was investigated to separate Pd(Ⅱ) from other metals.
It was clarified that almost perfect recovery of Pd(Ⅱ)can be attained by the multistage-countercurrent solvent extraction with EHO, when Pd(Ⅱ)concentration is approximately 0.005 mol/dm3 in the aqueous phese. The reaction stoichimetry is like Pd(Ⅱ): EHO: Cl- =1:2:2. It is impossible to strip the extracted Pd(Ⅱ) with EHO by using water, but the aqueous phase containing thiourea the perfect stripping of Pd(Ⅱ). Palladium (Ⅱ) with high purity can be obtained by the scrubbing process with water to remove small amounts of other metals present as an impurity in the organic phase.
BookA NOVEL SEPARATION TECHNOLOGY FOR A HEAVY RARE EARTH RESIDUE USING A SOLVENT IMPREGNATED RESINCo-authorJunji SHIBATA;Shigeno MATSUMOTO;Hideki YAMAMOTOSolvent Extraction Research and Development, Japan2000~Heavy rare earths, which are contained in small amount in ores such as bastnaesite and monazite, have been accumulated as a heavy rare earth residue without separation and purification due to lack of suitable methods. The heavy rare earth residue the seven rare earth elements Tb, Dy, Ho, Y, Er, Tm and Yb. A separation and recovery process for Dy, Y, Tm and Yb from a liquor produced by leaching the heavy rare earth residue was investigated by using a column method with a solvent impregnated resin. The solvent impregnated resin was prepared by impregnation with the organophosphorous extractant whose trade name is PC-88A of a macro porous resin, Amberlite XAD-7. It was almost impossible to separate the rare earths in simple adsorption and elution steps. However, the individual separation of Dy, Y, Tm and Yb from the leach liquor was achieved by first changing the eluent concentration gradually from pH2 to 2mol/dm3 HCl in the elution step, and secondly by using a development column and changing the eluent concentration in the elution step. A separation process flow sheet was proposed for the heavy rare earth residue by using the solvent impregnated resin method.
PapersInternal Structure and Thermal Behavior of Ag-NiO Composite Powders Prepared by Spray Pyrolysis
-Preparation of Ag-NiO composite powders by spray pyrolysis(2nd Report)-In refereedAcademic JournalCo-authorYAMAMOTO HidekiEPMA Analysis;Nickel;Silver;Nitrate;Composite Powders;Thermal Characterization;Spray2000~
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PapersA Novel Separation Technology for a Heavier Rare Earth Residue Using a Solvent Impregnated ResinIn refereedCo-authorJ.Shibata;S.Matsumoto;H.YamamotoSolvent Extraction Research and Development, JapanVol.7 pp.167-1752000~
PapersIn refereedCo-authorYAMAMOTO,Hideki;;;YAMAMOTO Hideki2000~
PapersStudies of Separation Behavior and Mechanism of Plastics, PVC and PET by Flotation MethodUnrefereedCo-authorY.Takami;J.Terada;S.Matsumoto;H.Yamamoto;J.ShibataTechnology Reports of Kansai UniversityNo.42, March pp.85-1002000~
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Chemical Reaction for Disposal of Waste Nitrogen Fluoride from Manufacturing Process of SemiconductorsIn refereedCo-authorH.Yamamoto;J.ShibataProceedings of World Congress on Integrated Resources ManagementVol.1 pp.141-1442000~
Application of Solvent Impregnated Resin to the Treatment of Heavier Rare Earth ResidueIn refereedCo-authorJ.Shibata;S.Matsumoto;H.YamamotoProceedings of The XXI International Mineral Processing Congress, Rome Italypp.C6-15-C6-212000~
A New Technology for Two Composite Powders with Solvent Extraction-Crystallization StrippingIn refereedCo-authorJ.Shibata;H.YamamotoSecond International Conference on Processing Materials for Properties, San Franciscopp.435-4382000~
Disposal of Waste Fluoride and Chloride Gases in the Manufacturing Process of SemiconductorIn refereedCo-authorH.Yamamoto;J.ShibataSecond International Conference on Processing Materials for Properties, San Franciscopp.685-6882000~
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PapersSolvent Extraction of Copper from Chloride Solution with 2-Ethylhexanal OximeIn refereedAcademic JournalCo-authorJunji SHIBATA;Satoshi MAMIYA;Shigeno MATSUMOTO;Hideki YAMAMOTOSHIGEN-TO-SOZAI1999~There has been a trend to switch from pyrometallurgy to hydrometallurgy in copper refining of copper sulphide ores since pyrometallurgy process needs a huge amount of energy and is harmful to the environment. In this study, focusing on the extraction selectivity EHO(2-ethylhexanal oxime), which extracts Cu, Ni and Pd from chloride solution, the mechanism and behavior of Cu2+ extraction with EHO from the leached solution of copper sulphide ores with ferric chloride solution and stripping of copper with water were investigated in order to clarify the possibility of an environmentally friendly hydrometallurgical process.
PapersAnalysis of Flow Property Using Falling Slender Cylindrical Needle in Power Law FluidIn refereedAcademic JournalCo-authorHIDEKI YAMAMOTO;JUNJI SHIBATA1999~A simple technique for the flow property analysis of a power law fluid with the terminal velocity of a falling body in a viscous fluid had been developed for process control of a chemical plant. A falling needle viscometer was used as the experimental equipment, and a slender hollow cylindrical needle of which both ends are hemispherical was applied to falling body. As the fluid model of laminar flow, the fluid behavior between the falling needle surface and container wall was analyzed, and Stokes type equation was introduced for the calculation. Shear stress and shear rate at the surface of each needle were calculated with the terminal velocity of the falling needle and the density difference between the sample fluid and needle.
Analisis of the flow property in power law fluid was carried out in accordance with the following procedure.
(1) Measurement of density difference between fluid and needle.
(2) Measurement of terminal velocity of falling needle in fluid.
(3) Calculation of shear stress and shear rate at needle surface.
(4) Determination of parameters in constituted equation.
(5) Drawing of constituted flow curve.
As for this analysis, Ut-(s-f)and log Ut-log(s-f)diagrams which were discribed by use of the experimental data, are very similar to that of - and log-log diagrams, respectively. It is found that the flow curve configuration for a power law fluid can be predicted from the data of terminal velocity and density difference. As a result of experiments of some model fluids, it is verified that the method using a viscometer presented here could be effectively applied to high viscosity fluid and that the application is available for such Power law fluid as polymer solution and suspensions containing fine particles. Further, an analytical method by use of a computer system is also presented for the fluids.
PapersHydrothermal Synthesis of Zeolite from Coal Fly Ash by Using NaOH/Na2CO3 SolutionIn refereedAcademic JournalCo-authorYasuyoshi NISHIKAWA;Norihiro MURAYAMA;Hideki YAMAMOTO;Junji SHIBATA;Kazuo OGAWASHIGEN-TO-SOZAI1999~Zeolites have been synthesized through hydrothermal reaction of coal fly ash with alkaline solutions in order to facilitate effective use of the fly ash generated from the coal power stations. The properities of synthesized were examined by X-ray diffraction, and characterized by cation exchange capacity(CEC)and specific surface area. Each of NaOH solution or Na2CO3 solution was applied to test the effects of alkali type on hydrothermal reaction.
The reaction conditions established in the present work were the ratio of solid and liquid, 1:4 and reaction temperature, 393 K for the favored synthesis of zeolite in only few hours without any pretreatment. Only zeolite P was synthesized when 0.5-3.0 mol/dm3 NaOH was used, whereas both zeolite P and hydroxysodalite were produced in the case of NaOH solution of 4.0 mol/dm3. CEC value of 350 meq/100 g of the zeolite P synthesized with 2.0 mol/dm3 NaOH was sufficient for a cation exchanger. SEM photographs showed the growth of zeolite on the surface of the undissolved fly ash, resulting texture of amorphous fly ash covered with the crystallized zeolite. Sodium carbonate solution of 1.0 mol/dm3 alone failed the synthesis reaction of zeolite, whereas addition of more than 15% of NaOH proceeded the reation. The thickness of zeolite layer depended on the amount of NaOH.
KEY WORDS: Fly Ash, Zeorlte, Hydrothermal Reaction, Cation Exchange, Sodium Hydroxide, Sodium Carbonate
PapersSolvent Extraction of Copper from Chloride Solution for Environmantally Friendly Copper Hydrometallurgical ProcessIn refereedAcademic JournalCo-authorJunji SHIBATA;Shigeno MATSUMOTO;Satoshi MAMIYA;Takahiro KAWAHARA;Hideki YAMAMOTOSHIGEN-TO-SOZAI1999~The present refining of copper from sulfide copper ores by pyrometallurgical process is lack for the environmental concerns, that is, generation of harmful SO2 gas and high energy consumption. Considering our environmental aspects and saving the energy, we directed our attention to recover Cu by using the more advantageous L-SX-EW(Leaching-Solvent Extraction-Electrowinning)method. This hydrometallurgical L-SX-EW method can be designed as a closed system and lessen the wastes from the process. Based on the investigation we have already reported with respect to the extraction mechanism of Cu2+ with EHO(2-ethylhexanal), in this study the separation of Cu2+ was examined from the leached solution obtained after leaching copper sulfide ores with ferric chloride solution, and the realizability of the environmentally friendly hydrometallurgical process was also investigated.
The extractant EHO is very effective to separate Cu2+ from the leached solution containing Fe2+, Fe3+ and Zn2+. Cupric ions are selectively extracted in the organic phase at chloride ion concentration, 3-5 mol/dm3, while Fe3+ and Zn2+ are not transferred into toe organic phase. The stages and phase ratio(A/O)required to attain the desired Cu2+ recovery are estimated to be 2-stage countercurrent extraction with the phase ratio(A/O) of 1.5. In order to strip Cu with water from the organic phase, 6-stages countercurrent stripping with the phase ratio(O/A)of 1.8 are required. By the extraction and stripping operation, 10 g/dm3 Cu2+ is purified and concentrated to 25 g/dm3 Cu2+.
CommentaryCo-authorYAMAMOTO,Hideki1998/3~
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PapersRemoval and Mechanism of Toxic Organic Compounds from Aqueous Solutions using Continuous Solvent SublationIn refereedAcademic JournalCo-authorShigeno MATSUMOTO;Hideki YAMAMOTO;Junji SHIBATA1997/10~Removal tests of toxic organic compounds from aqueous solutions have been carried out using the continuous solvent sublation method. Naphethalene(NAP)and penthachlorophenol(PCP)are chosen as a model compound to be removed, and n-octanol is used as a phase for their recovery. In order to simulate the effect of physical and chemical properties of the organic compounds on the removal, the removal model for continuous solvent soblation is constructed on the basis of batch solvant sublation model.
The concept of the removal model for continuous operation is mainly constructed by two terms, that is, the removal by bubbles such as adsorption on the bubble, entrainment with boundrary layer of bubble, vaporization into bubble, and the mass transfer to the organic phase placed at the upper part of the sublation column.
The optimum operating conditions for the continuous solvent sulvent sublation such as the gas and aqueous flow rate and the organic phase volume are discussed for evalution of its practical utilization.
Academic presentationCo-authorYAMAMOTO,Hideki1997/9~
PapersApplication of Soave-Redlich-Kwong Equation of State in Combination with Wilson Parameters Having Controlled Influence by Temperature to Estimation of Vapor-Liquid EquilibriumIn refereedAcademic JournalCo-authorHideki YAMAMOTO;Kazuyuki MIYATA;Norihisa SASAMAYA;Junji SHIBATASekiyu Gakkaishi1997/3~The attracting term in Soave-Redlich-Kwong(SPK) equation was modified, using the Heidemann and Kokal mixing rule at zero pressure to estimate the vapor-liquid equilibrium of some alcohol systems, in the range of respective critical points. In this work, Wilson parmeters were applied to calculate the excess Gibbs energy, and expressed by respective curve of secondary degree of reciprocal remperature.
Vapor-liquid equilibrium of ethane-propane, CO2-ethane, CO2-propane, methanol-water and ethanol-water systems could be estimated from the data of low pressure vapor-liquid equilibrium, using SRK equation in combination with Wilson parameter, within average deviation of 5.35%.
PapersApplication of Solvent Sublation for Removal of Toxic Organic Compounds from Aqueous SolutionIn refereedAcademic JournalCo-authorShigeno MATSUMOTO;Yasutaka KIDA;Hideki YAMAMOTO;Junji SHIBATASHIGEN-TO-SOZAI1997~
PapersVapor-Liquid Equilibria for Alcohol + Alcohol + Sodium Iodide at 298.15 KIn refereedAcademic JournalCo-authorHideki Yamamoto;Koji Fukase;Junji ShibataJOURNAL OF CHEMICAL & ENGINEERING DATAⓇ1996~Vapor-liquid equilibria for methanol + propan-1-ol + NaI, methanol + propan-2-ol + NaI, ethanol + propan-1-ol + NaI, and ethanol + propan-2-ol + NaI systems were measured at 298.15 K using a static method. The apparatus was tested by comparing results for ethanol + water and ethanol + water + CaCl2 with literature results. Results were tested for thermodynamic consistency by Herinton's area test and point test. NaI exerted a salting-in effect on all binary alcohol solutions and the order of the salt effect of NaI was methanol + ethanol < ethanol + propan-1-ol < ethanol + propan-2-ol < methanol + propan-1-ol < methanol + propan-2-ol. Hála's model was applied for the correlation of four alcohol + alcohol + salt systems using observed data. Calculated β values in Hala's equation were between 2.8 and 3.9 for the four alcohol + alcohol + NaI systems.
PapersSeparation of Dy, Y, Tm amd Yb from Heavier Rare Earth Residue by Column Method Using Solvent Impregnated Resin -Separation of rare earth with solvent impregnated resin(3rd Report)-In refereedAcademic JournalCo-authorJunji SHIBATA;Shigeno MATSUMOTO;Norihiko NAKAYAMA;Miki MASHIMO;Hideki YAMAMOTOSHIGEN-TO-SOZAI1996~Heavier rare earth which is contained in a small amount in ores such asbastna site and monazite has been accumulated as heavier rare earth residue without doing separation and purification due to its small damend. The heavier rare earth residue includes seven rare earth elements such as Tb, Dy, Ho, Y, Er, Tm and Yb. The separation and recovery process of Dy, Y, Tm and Yb from leached solution of the heavier rare earth residue was investigated by using a column method with a solvent impregnated resin. The solvent impregnated resin was prepared by impregnation of organophosphorous extractant whose trade name is PC-88A into a macro prous resin. Amberlite XAD-7.
It was almost impossible to separate them in simple adosorption and elution steps. However, we attained to individually separate Dy, Y, Tm and Yb from the leached solution first by changing eluent concentration from pH 2 to 2N HCl in the elution step, and secondly by using a development column and changing eluent concentration in the elution step. The separation process flow was proposed for raw materials containing rare earth by using the conventional solvent extraction method and solvent impregnated resin method.
PapersFlotation separation of plastics using selective depressantsIn refereedAcademic JournalCo-authorJ.Shibata;S.Matsumoto;H.Yamamoto;E.KusakaINTERNATIONAL JOURNAL OF MINARAL PROCESSING1996~Four important plastics, namely polyvinyl chloride(PVC). polycarbonates(PC), poly acetal(POM)and polyphenylene ether(PPE)were successfully separated from their synthetic mextures using common wetting agents like sodium ligninsulfonate, tannic acid, Aerosol OT and saponin. The efficient flotation separation amongst these naturally hydrophobic polymers could be attributed to the selective reduction in hydrophobicity(measured as the drop in contact angle)as a consequence of surfactant adsorption. The relative order of floatability measured with the help of column flotation experiments in the presence of various depressants selected for this study was found to be PPE > POM > PC >PVC, a trend consistent with the critical surface tension values determined for these solids except PPE. A flowsheet was developed on the basis of flotation results. It was possible to accomplish almost a perfect separation using the proposed flowsheet involving heavy media separetion followed by flotation in two stages.
PapersExtraction of Au(Ⅲ), Pd(Ⅱ)and Rh(Ⅲ)with N-Benzyl Aniline and Their Stripping BehaviorIn refereedAcademic JournalCo-authorToshiharu OHARA;Shigeno MATSUMOTO;Hideki YAMAMOTO;Junji SHIBATA;Yoshinari BABASolvent Extraction Research and Development, Japan1996~The selective separation by solvent exraction of Au(Ⅲ), Pt(Ⅳ), Pb(Ⅱ) and Rh(Ⅲ) from hydrochloric acid with N-benzyl aniline(NBA) was investigated. Up to 80% of gold was extracted at an HCl concentration of more than 3.0mol/dm3. Palladium was extracted quantitatively at an HCl concentration of less than 1.0mol/dm3. Up to 60% of platinum was extracted at about 1.0mol/dm3 HCl concentration.
Stripping of these metals was carried out using hydrochloric acid and thiourea as stripping agents. Pt could be easily stripped with water, but more than 4.0mol/dm3 hydrochloric acid was necessary for quantitative stripping of Pd. Thiourea was an excellent stripping agent for Au and Pd even at low concentrations.
The extraction equilibria of Au(Ⅲ), Pt(Ⅳ), and Pd(Ⅱ)may be expressed as follows:
AuCl4- + R2HNH+Cl- ⇄ [R2HNH+AuCl4-]org + Cl-
PdCl42- + 2[R2HN]org ⇄ [(R2HN)2PdCl2]org + 2Cl-
PtCl62- + 2R2HNH+Cl- ⇄ [(R2HNH+)2PtCl62-]org + 2Cl-
PapersAn Investigation on Pumping Effect in Pump-mix Type Mixer-settler ExtractorIn refereedAcademic JournalCo-authorJunji SHIBATA;Hideki YAMAMOTO;Shigeno MATSUMOTO;Yoshikazu MIYAKESHIGEN-TO-SOZAI1996~The suction and extrusion pressures were measured by using a vaned disk and a plate turbine as an impeller of mixer-settler extrator. The sution effect by a vaned disk and extrusion effect by a plate turbine are strongly dependent on the rotation speed, and they slightly decrease with an increase in the flow rate due to the pressure drop. When the flow rate is zero, the maximum suction and extrusion pressures are obtained. The both pressures at a certain flow rate are in good agreement with the difference between the maximum pressure and the total pressure drop. The maximum suction and extrusion pressures are nearly proportional to the third power of rotation speed. The suction pressure is also dependent upon the distance from the vaned disk to the bottom of the mixing space, and in the same manner the extrusion pressure depends on the distance from the plate turbine to the extrusion pipe of the mixing space. When the distance is shorter, the effect becomes higher. If the rotation speed is fixed, the desired suction and extrusion pressures are obtained by adjusting the distance.
PapersFeasibility of Flotation to Separation of Waste PlasticsIn refereedAcademic JournalCo-authorJunji SHIBATA;Shigeno MATSUMOTO;Eishi KUSAKA;Hideki YAMAMOTO;Yoshio MOROMOTOSHIGEN-TO-SOZAI1996~As part of studies on the development of separation process for efficiently separating waste plastics, the applicability of flotation method to the separation of inherently hydrophobic plastics has been investigated. For optimizing the flotation operation conditions, floatability measurements of plastics was carried out in solutions including wetting-agent, and flotation separation using two plastics mixture as well. Moreover, the dense media separation and flotation process, which has been proposed in this investigation, were examined in terms of the plastic grade and percent recovery. Polyvinyl chloride(PVC), polycarbonate(PC), polyacetal(POM)and polyphenylene ether(PPE)were used as test polymers, and tannic acid, sodium ligninesulfonate, polyoxyethylene lauryl ether, Aerosol OT and saponin as wetting-agents.
The floatability measurements showed that the increased concentration of wetting-agent brings about the decrease in percent floatability of each of polymers ; the might be explained in line with adsorption behavior of surface-active species. Separation flotation using two plastics mixture indicated that one plastic is sufficiently separated from another in an optimum concentration of wetting-agent. Furthermore, the wetting-agent mixture was found to improve the efficiency of the separation flotation. Finally, according to the results obtained from the flotatoin tests, a dense media separation and flotation process was proposed and applied to the differential separation of the four plastics mixture. It was found that the proposed satisfactorily separated one plastic from others with high grade and recovery at each of the operations; the 100% PPE floats is obtained with 100% recovery in the dense media separation, the 95.7% PVC sinks with 90.7% PVC recovery in the first flotation, and the 87.6% POM floats and the 90.3% PC sinks with 99.2% POM and 83.6% PC recoveries, respectively, in the second flotation. We suppose this separation process to be feasible for recycling waste plastics.
PapersPerformance of Thermal Energy Storage Unit Using CaCl2-NH3 Systems Mixed with Ti The Canadian Journal of Chemical EngineeringIn refereedAcademic JournalCo-authorYAMAMOTO HidekiThe Canadian Journal of Chemical EngineeringVol.68, pp.948-9511995/9/20~
PapersAssociation Model in Tri-n-Octylamine(TOA)-Carboxylic Acid-Diluent SyatemsIn refereedAcademic JournalCo-authorHideki YAMAMOTO;Yasuharu NISHI;Junji SHIBATA1995/3~The prediction of the association mechanism in the tri-n-octylamine(TOA)-carboxylic acid(acetic acid or propionic acid)system was carried out using an association model based on the excess volume. Furthermore, a diluent effect on the association equilibrium of these solvent mixtures was tested by making use of three different diluents(benzene, hexane and ethanol).
In the experiments, the excess volume difference(VE)was measured at 298.15 K for the solvent mixtures of TOA and carboxylic acid, and diluents. Then, overall and consecutive equilibrium constants of association(βi and Ki)were determined for TOA-carboxlylic acid-diluent ternary systems. The dominant associating species in the TOA-carboxylic acid-diluent system were determined using overall equilibrium constants. It was found that the dominant associating species in the TOA-carboxylic acid systems were BA2 and BA3(B:TOA, A:carboxylic asid)and similar results were obtained in the TOA-carboxylic acid-benzene or hexane systems. However, the dominant associating in the TOA-carboxylic acid-ethanol system varied from BA2 and BA3 to BA.
PapersSalt Effect of CaCl2, NH4I and NaI on Vapor-Liquid Equilibrium of Ethanol + Water System at 298.15 KIn refereedAcademic JournalCo-authorHIDEKI YAMAMOTO;TAMOTSU TERANO;MASAHIKO YANAGIWSAWA;JUNJI TOKUNAGATHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING1995~Salt effect on vapor-liquid equilibrium for the ethanol + water system was measured at 298.15 K using an experimental apparatus based on the static mathod. The salting-out effect of CaCl2, NH4I and NaI on the ethanol + water system follows the order of CaCl2 > NaI > NH4I. The observed experimental data were correlated by the use of a semiempirical model proposed by Hála(1983)with an accuracy of З2.13%. The application of Hála's model was confirmed in the ethanol + water system to be added the salts other than CaCl2 at 298.15 K.
On a mesure I'éffet du sel sur I'équilibre liquide-vapeur pour le système éthanol + eau à 298.15 K au moyen d'un appareillage expérimental beaé sur la méthode statique. L' effet relargant des CaCl2, NH4I et NaI sur le système éthanol + eau suit I'ordre de CaCl2 > NaI > NH4I. Les donnees experimentales ont été corrélées grâce á un modéle semiemprique proposé par Hála a été confirmée dans le système éthanol + eau pour l'ajout de sels autre que le CaCl2 á 298.15 K.
PapersVapor-Liquid Equilibria for Methanol + Ethanol + Calcium Chloride, + Ammonium Iodide, and + Sodium Iodide at 298.15 KIn refereedAcademic JournalCo-authorHideki Yamamoto;Tamotsu Terano;Yasuharu Nishi;Junji TokunagaJOURNAL OF CHEMICAL & ENGINEERING DATA1995~Vapor-liquid equilibria for methanol + ethanol + CaCl2, + NH4I, and + NaI were measured at 298.15 З 0.05 K using a static method. The data obtained in this apparatus were confirmed by comparison with the literature data of ethanol + water and ethanol + water + CaCl2 and tested for thermodynamic consistency. Any salt used in this work exerted salting-in effect on the methanol + ethanol system, the magnitude of which was CaCl2 >NaI > NH4I. The observed data were correlated by use of Hála's equation, and β was determined for each system. The calculated result of each system reproduced experimental data within an accuracy of З2.12% in vapor-phase mole fraction. From the results of comparison of β obtained in this work with the kind of salt additive for methanol + ethanol and ethanol + water systems, it was found that β depended mainly on the kind of salt but not on the kind of solvent mixture. The application of Hála's model for an alcohol + alcohol + salt system was confirmed at a temperature of 298.15 K.
PapersCo-authorYAMAMOTO,Hideki1994/9~
Academic presentationCo-authorYAMAMOTO,Hideki1994/9~
Academic presentationCo-authorYAMAMOTO,Hideki1994/7~
Academic presentationCo-authorYAMAMOTO,Hideki1994/7~
PapersYAMAMOTO,Hideki1994/7~
PapersSolubility of Argon in Acetone + Water Mixed Solvent at 288.15, 298.15 and 308.15 KIn refereedAcademic JournalCo-authorHIDEKI YAMAMOTO;JUNJI TOKUNAGATHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING1994/6~Solubilities of argon were determined in acetone + water mixed solvent over the full range of composition using a static method. The gas solubilities were measured at three temperatures of 288.15, 298.15 and 308.15 K. The solubility dependence on the temperature in the mixed solvent was measured and discussed, and the similarity between excess quantities of mixed solvent and those of gas solubilities was examined.
The order of gas solubility of argon in acetone + water mixed solvent at the three defferent temperatures was 288.15 > 298.15 > 308.15 K in the composition range of 0 ≦ X2 ≦ 0.15. However, the reverse relationship with temperature was observed in the range of composition of 0.15 < X2 ≦ 1.0. For all solubility curves, maximum and minimum values of solubility were observed at lower temperatures, but not at higher temperatures. Furthermore, the excess Ostwald coefficients on the basis of volume fraction which express the non-ideality of gas solubility in non-ideal solutions were defined, and they were expressed by a polynomial equation of the Redlich-Kister(1948)type.
On a determiné les solubilités de I'argon dans un solvant mixte acétone+ eau pour une vaset gamme de compositions au moyen d'une méthode statique. Les solubilités de gaz ont été mesureésà trois temperatures de 288.15, 298.15 et 308.15 K. La dépendance des solubilités sur la témperature dans le solvant mixte a été mesurée et analysee, et on a examiné la similarité entre des quantités excédentaires de solvant et celles des solubilités de gaz.
L'ordre de solubilité de gaz de l'argon dans le solvant mixte acétone + eau aux trois températures est de 288,15 > 298.15 > 308.15 K dans la gamme de composition 0 ≦ X2 ≦ 0.15. Cependant, la relation inverse a été observée avec la température dans la gamme de composition 0,15 ≦ X2 ≦ 1.0. Pour toutes les courbes de solubilité, des valeurs maximales et minimales de solubilité ont été observees aux températures inférieures, mais non aux températures superieures. En outre, on a déterminé les coefficients d'excés d'Oswald sur la base de la fraction volumique qui exprime le caractére non idéal de la solbilite de gaz dans des solutions non idéales; ces coefficients sont exprimés par une equation polynomiale de type Redlich-Kister(1948).
PapersCo-authorYAMAMOTO,Hideki1994/6~
PapersSolubilities of Argon, Oxygen and Nitrogen in 1,2-Propanediol + Water Mixed Solvent at 298.15 K and 101.33 kPaIn refereedAcademic JournalCo-authorHideki YAMAMOTO;Hiroyuki KAMEI;Junji TOKUNAGAJournal of Chemical Engineering of Japan1994~Solubilities of argon, oxygen and nitrogen were determined in 1.2-propanediol+water mixed solvent over the full range of composition by a static method. Gas solubility measurements were carried out at a temperature of 298.15 K and pressure of 101.33 kPa. Both the exccess quantity referring to the Ostwald coefficient and to the excess volume of solvent mixture showed similar relation having minima against the volume fraction composition of 1,2-propanediol.
The order of gas solubility expressed by the Ostwald coefficient in 1,2-propanediol+water mixied solvent was argon > oxygen > nitrogen in full range of composition. Furthermore, the excess Ostwald coefficients on the basis of volume fraction which express the non-ideality of gas solubility in non-ideal solutions were defined, and excess Ostwald coefficient of these three solute gases in 1,2-propanediol+water mixed solvent showed one parabolic curve against volume fraction of 1,2-propanediol. This result means that excess Ostwald coefficients of these gases do not depend on the type solute gas, but on solvent. This property was similar to that of monoalcohol aqueous solutions.
PapersSolubilities of Nitrogen and Oxygen in 1,2-Ethanediol + Water at 298.15 K and 101.33 kPaIn refereedAcademic JournalCo-authorHideki Yamamoto;Junji TokunagaJORNAL OF CHEMICAL & ENGINEERING DATA1994~Solubilities of nitrogen and oxygen were determined on the 1,2-ethaediol + water solution over the full range of composition by a static method. The gas solubility was measured at 298.15 K and 101.33 kPa. Both the excess Ostwald coefficient and the excess volume of the mixed solvent showed similar dependencies on the volume fraction. The observed values of oxygen and nitrogen in 1,2-ethanediol + water were expressed by the Ostwald coefficient. From the result of the solubility of argon by Ben-Naim and our observed solubilities of nitrogen and oxygen, the order of gas solubility was argon > oxigen > nitrogen in the full range of composition. Furthermore, the excess Ostwald coefficients on the basis of the volume fraction which express the nonideality of gas solubility in nonideal solutions were defined, and excess Ostwald coefficients of these three solute gases in 1,2-ethanediol + water showed the same curve against the volume fraction of 1,2-ethanediol. This result means that the kind of solute gas had no effect on the excess Ostwald coefficient defined in this work. This property was identical with that for monoalcohol aqueous solutions.
PapersSolubility of Helium in Methanol + Water, Ethanol + Water, 1-Propanol + Water, and 2-Propanol + Water Solutions at 25℃In refereedAcademic JournalCo-authorHideki Yamamoto;Kenichi Ichikawa;Junji TokunagaJOURNAL OF CHEMICAL AND ENGINEERING DATA1994~The solubility of helium was measured in four aqueous alcohol solutions (methanol + water, ethanol + water, 1-propanol + water, and 2-propanal + water systems) over the full range of composition at 25℃ and 101.325 kPa. Both the excess quantity referring to the Ostwald coefficient and that referring to the excess volume show similar minima as a function of the volume fraction of alcohol.
PapersDensities and Viscosities of NH4B-NH3 and NH4I-NH3 SystemsIn refereedAcademic JournalCo-authorHideki Yamamoto;Junji TokunagaJOURNAL OF CHEMICAL AND ENGINEERING DATA1991~Densities of the NH4Br-NH3 and NH4I-NH3 systems in liquid phase have been measured over a wide range of temperatures and concentrations. Densities of saturated solutions of the NH4Br-NH3 and NH4I-NH3 systems have also been measured over the temperature range from 0 to 76.5℃ and from 0 to 69.5℃, respectively. The accuracy of this measurement was З0.1%. Observed densities were expressed as a function of temperature and concentration by means of polynomial equations. These equations could calculate values to an accuracy within З0.5% of the observed data. For the sake of the viscometry of these systems, a falling-body viscometer with use of a He-Ne laser was assembled. The viscosities of NH4Br-NH3 and NH4I-NH3 systems were measured in the ranges of mass percent of ammonium hallde from 10.0% to 59.8% and from 9.81% to 70.1% under the wide temperature range respectively. The accuracy of these viscometry was within З1.2% deviation against standard liquid to callbrate this viscometer.
PapersPerformance of Thermal Enargy Storage Unit Using CaCl2-NH3 System Mixed with TiIn refereedAcademic JournalCo-authorHIDEKI YAMAMOTO;YUUKI SAKAMOTO;SEIJI SANGA;JUNJI TOKUNAGATHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING1990/12~
PapersMeasurement of Heat of Mixing for Ammonium Chloride + Ammonia System at 25℃In refereedAcademic JournalCo-authorHIDEKI YAMAMOTO;SEIJI SANGA;JUNJI TOKUNAGATHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING1988/2~Heat of mixing for ammonium chloride ammonia at 25℃ was determined in the concentration range 0-50 wt% NH4Cl. It was calculated from the differential heat of solution observed in this work and the differential heat of dilution estimated from activities of solvent. A twin isoperibol calorimeter consisting of two stainless Dewar vessels was used at a relaively high pressure(up to 1.5 MPa). The accuracy of this calorimetry was examined by measuring the heat of solution for tris-(hydrowymethyl)aminomethane(THAM)in 0.1 kmol/m3 HCl at 25℃, and satisfactory agreement within 1.1% between experimental and literature value was obtained. The reproducibility for the experiment was within 2.8%.
On a déterminé la chaleur de mélange du chlorure d'ammonium dans de l'ammoniac liquide à 25℃ pour des concentrations de NH4Cl comprises entre 0 et 50%. Cette valeur a été calculée à partir de la chaleur de solution différentielle observée dans cetteétude ainsi que la chaleur de dilution différentielle estiméeà partir de l'activité du solvant. On a utilisé, à une pression relativement élevée(jusqu'à 1,5 MPa), un calorimétre isopéribol jumelé composé de deux cuves Dewar en acier inoxy dable. La présision du calorimétre a été vérifiée en mesurent la chaleur de solution du tris-(hydroxyméthyl)aminométhane(THAM)dans 0,1 kmol/m3 de HCl à 25℃; on a trouvé un bon accord(variation de 1.1%)entre les valeurs expérimentales et les valeurs publiées. L'erreur expérimentale est inférieure à 2.8%.
PapersVapor Pressures of Ammonium Bromide + Ammonia and Ammonium Iodide + Ammonia SolutionsIn refereedAcademic JournalCo-authorHideki Yamamoto;Seiji Sanga;Junji TokunagaJOURNAL OF CHEMICAL AND ENGINEERING DATA1988~Vapor pressures for ammonium bromide + ammonia and ammonium iodide + ammonia solutions were measured in the concentration ranges of 10-65 wt % and 10-75 wt % at various temperatures, respectively. The observed vapor pressures were fitted to Antoine's equation, using the method of least squares. Furthermore, Antoine's constants for both solutions were expressed as fourth-degree functions of concentration of ammonium halides. In addition, vapor pressures for saturated ammonia solutions of ammonium hallde were measured over the temperature range of 0-80℃. The calculated vapor pressures by these equations at 25℃ were compared with Hunt's data, and good agreement was obtained. Vapor pressure measurements were carried out by using a strain gauge transducer(up to 2.0 MPa), and the accuracy of this measurement was З0.001 MPa. The vapor pressures calculated by Antoine's equation agreed with the observed values within a deviation of З2.7%.
PapersSolubilities of Oxygen and Nitrogen in Acetone-Water Mixed SolventIn refereedAcademic JournalCo-authorKiyoyuki Tsuji;Kenichi Ichikawa;Hideki Yamamoto;Junji TokunagaReprinted from Kagaku Ronbunshu1987~The solubilities of oxygen and nitrogen in acetone-water, mixed solvent were measured at 20, 30 and 40. Among these solubility values except for nitrogen at 40, maximum and minimum values exist in the composition range of about XA<0.1, and the solubilities increased monotonously against acetone mole fraction of mixed solvant(XA)in the range of about XA>0.1.
For these systems, the similarity was recognized between the excess solubility on the Ostwald coefficient expression basis and the ratio of the excess molar volume to the ideal one in the composition range of 0.2<A<1.0.
PapersPerformance Test of Absorption Air-Cooling Unit Using NH4Br-NH3 and NH4I-NH3 SystemsIn refereedAcademic JournalCo-authorHideki Yamamoto;Seiji Sanga;Junji TokunagaI&EC RESEARCH1987~An absorption air-cooling apparatus using NH4Br-NH3 and NH4I-NH3 systems was designed and tested in order to most effectively utilize low energy(i.e., solar energy and hot drain). This apparatus used liquid ammonia as the refrigerant and ammonium halides(NH4Br or NH4I)as the absorbent, and this absorption refrigerator permitted air cooling and refrigeration. Furthermore, a rectifying tower for recovery of refrigerant from ammonia solution was not needed. Coefficients of performance(C.O.P.)of the apparatus using these two ammonia solution systems were determined for the same operating conditions, and these values are compared and discussed. The effect of Tg, Tc, and N on C.O.P. was investigated under various conditions. These values were also compared with the ones calcuated from the enthalpy-concentration charts for both the NH4Br-NH3 and the NH4I-NH3 systems.
PapersSolubilities of Ammonium Iodide, Ammonium Bromide, and Ammonium Iodide-Ammonium Bromide Mixture in Liquid AmmoniaIn refereedAcademic JournalCo-authorHideki Yamamoto;Junji Tokunaga;Seiji SangaJOURNAL OF CHEMICAL AND ENGINEERING DATA1986~Solubilities of ammonium iodide and ammonium bromide in liquid ammonia were determined in the temperature range 270.0-350.0 K. Solubilities of these solutes in liquid ammonia increased with the temperature, and the values of weight percent solubility increased from 77.34 to 83.01 wt % for ammonium iodide, and from 68.71 to 73.19 wt % for ammonium bromide. Solubilites of the mixtures of ammonium iodide and ammonium bromide(four weight ratios of NH4I/NH4Br = 0.37, 0.80, 1.48, and 2.95)in liquid ammonia were also determined in the temperature range 270.0-350.0 K. The relation between temperature and weight percent solubility for ammonium iodide in liquid ammonia was shown by a smooth curve, but a bend point appeared on the solubility curve for ammonium bromide or its mixture with ammonium iodide in liquide ammonia. With increasing weight ratios of ammonium iodide to ammonium bromide, the bend point on the solubility curve gradually moved toward lower temperature.
PapersIn refereedAcademic JournalCo-authorYAMAMOTO,Hideki;YAMAMOTO HidekiChemistry Express1986~
PapersEnthalpy-Concentration Charts for NH4Br-NH3 and NH4I-NH3 SystemsIn refereedAcademic JournalCo-authorHideki Yamamoto;Akira Kurata;Seiji SangaReprinted from Kagaku Kogaku Ronbunshu1984~The specific heats and the differential heats of solution for NH4Br-NH3 and NH4I-NH3 Systems were measured in order to construct enthalpy-concentration charts for these systems.
A twin calorimeter was used. Specific heat measurements were carried out at concentrations of ammonium bromide or ammonium iodide from 0 to 70 wt% and temperatures from 10 to 50. Differential heats of solution were measured over a concentration range from 0 to 70 wt% at 25. Integral heats of mixing were calculated from the differential heats of solution observed in this work and the differential heats of dilution estimated from the acitivities of these solution systems.
The accuracy of the twin calorimeter was examined by measuring the heat of solution of tris(hydroxymethyl)aminomethane(THAM)in 0.1 N HCl(aq.)and 0.1 N NaOH(aq.)at 25 The maximu deviation from literature data was within 3%.
PapersSpecific Heats of NH4Br-NH3 and NH4I-NH3 systemsIn refereedAcademic JournalCo-authorAkira Kurata;Hideki Yamamoto;Masao Obata;Seiji Sanga1983~The specific heats of NH4Br-NH3 and NH4I-NH3 systems were measured in a range of concentrations from 10 wt% to 70 wt% at 25.
For the measurements, a twin calorimeter consisting of two metallic Dewar cells of the same size employed at high pressure(3-13 105 Pa).
PapersPerformance Test of Absorption Air-Cooling Unit Using NH4Br-NH3 and NH4I-NH3Systems Industrial Engineering Chemistry and ResearchIn refereedAcademic JournalCo-authorYAMAMOTO Hideki
PapersSolubiluties of Argo, .Nitrogen and Oxygen in 1,2-Propanediol+Water System 298.15K and 101.33kPa Journal of Chemical Engineering of JapanCo-authorYAMAMOTO Hideki
BookAssociation Model in Tri-n-Octylamine(TOA)-Calboxylic Acid-Diluent Systems Solvent Extraction Research and Development, JapanCo-authorYAMAMOTO Hideki
BookSalt Effect of CaC2.NH4I and NaI on Vapor-Liquid Equilibrium of Ethanol+Water System at 298.15K The Canadian Journal of Chemical EngineeringCo-authorYAMAMOTO Hideki
BookDensity and Excess Moral Volume of Tri-n-Octylamine+Proponic Acid+Diluent at 298.15K Journal of Chemical and Enginneing DataCo-authorYAMAMOTO Hideki
BookVapor-Liquid Equilibria for Alcohol+Alcohol+Sodium Iodide at 298.15K Journal of Chemical and Engineering DataCo-authorYAMAMOTO Hideki
BookCo-authorYAMAMOTO,Hideki
PatentsYAMAMOTO,Hideki
BookTheoretical Analysis for Flow Behavior of Rheological Fluids Using FNV Model The Fourth Asian Thermophysical Properties ConferenceYAMAMOTO Hideki
BookA New Correlation of Gas Solubility with Solvent Composition of Binary Mixed Solvents Using Unit Molecular Group Model 45th Canadian Chemical Engineering CoferenceYAMAMOTO Hideki
BookProperties of Gas Solubility in Binary Mixed Solvents Containing Waters as One Component The sixteenth Japan Symposium on Thermophysical PropertiesYAMAMOTO Hideki
PatentsYAMAMOTO,Hideki
BookDensity and Excess Molar Volume of Tri-n-Octylamine + Propionic Acid + Diluent at 298.15 KCo-authorHideki Yamamoto;Kazuhiko Sakamoto;Yoshio Bando;Sigeno Matsumoto;Junji ShibataJOURNAL OF CHEMICAL & ENGINEERING DATAⓇThe densities and excess molar volumes(VE)for tri-n-octylamine(TOA)+ propionic acid, TOA + diluent, and propionic acid + diluent binary systems were measured under the full range of composition at 298.15 K, respectively. The excess molar volumes of TOA + propionic acid + diluent ternary systems were also measured at 298.15 K. Benzene, toluene, p-xylene, ethanol, hexane, and cyclohexane were used as the diluent. The |V┏ss3┓E┏/ss3┓┏ss4┓MAX┏/ss4┓| of TOA + propionic acid is found to be about 6 cm3・mol-1 at XA = 0.75. The maximum values of excess molar volume(V┏ss3┓E┏/ss3┓┏ss4┓MAX┏/ss4┓)for the ternary systems showed smaller values than that of TOA + propionic acid.
BookVapor-Liquid Equilibrium of Propan-2-ol + Propan-1-ol + Sodium Iodide at 298.15 KCo-authorHideki Yamamoto;Junji ShibataJOURNAL OF CHEMICAL & ENGINEERING DATAⓇThis paper presents vapor-liquid equilibrium data for the propan-2-ol(1)+ propan-1-ol(2) + NaI(3)ternary system measured at 298.15 K using a static mathod. The salting-out effect was observed for this ternary system. The VLE data were correlated by use of semiempirical model proposed by Hála. The parameters in Hála's equation were determined to be β=3.8, E13=35.14, E23=36.56, Ꮩ12=1.3404, Ꮩ21=0.7464, Ꮩ13=Ꮩ31=0.0774, and Ꮩ23=Ꮩ32=0.1796, respectively. This equation can describe the experimental values with an average deviation of 1.47%.
Research Activities Overseas
- OtherDevelopement of New Equation of State 1997United of America
Participation in International Conferences
- Canadian Chemical Engineering Conference 1999-2005
- Asian Pacific Confederation of Chemical Enginneing 1987
- Chem. Asia 89 Congress 1989
- The 2nd International Conference on New Energy Systems 1993
- Asian PacificConfederation of Chemical Engineering 1993
- The 4th Asian Thermophysical Properties Conference 1995
- The 16th Symposium on Thermophysical Properties 1995
- International Absorption Heat Pump Conference 1996
- Canadian Chemistry Onference 2004-2005
- ETCP2002 2002
Courses Taught
- Introduction to Entrepreneurship to acquire Ability
- Experiments of Analytical Chemistry
- Unit Operation I
- Thermal Engineering
- Foreign Language Reading in Engineering I
- Thesis Projects I
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- Freshmen Seminar
- Chemical Engineering Plant Design
- Sponsored Lecture (Beauty & Cosmetic Industry)
- Chemical and Environmental Risk
- Science of Phase Equilibrium
- Theory and Practice in Analyses II
- Current Issues on Energy and Environment
- SeminarI(Chemical, Energy and Environmental Engineering)
- SeminarII(Chemical, Energy and Environmental Engineering)
- Chemical, Energy and Environmental Engineering PBL I
- SeminarIII(Chemical, Energy and Environmental Engineering)
- SeminarIV(Chemical, Energy and Environmental Engineering)
- SeminarVIII(Chemical, Energy and Environmental Engineering)
- SeminarV(Chemical, Energy and Environmental Engineering)
- Science of Phase Equilibrium
- Human Activity and Ecology
- Current Issues on Energy and Environment
- Introduction to Entrepreneurship
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