SAKAGUCHI,Satoshi - Faculty of Chemistry, Materials and Bioengineering Department of Chemistry and Materials Engineering

SAKAGUCHI, Satoshi

Faculty, Department/Institute

Faculty of Chemistry, Materials and Bioengineering Department of Chemistry and Materials Engineering

Academic status (qualification)

Professor Apr. 1,2013

Graduate Degrees・University

Kansai University Master's Degree Program 1995 Completed

Academic Degrees

Doctor of Engineering Mar. 2001 Kansai University

Homepage Address, E-mail Address

Homepage Address：http://orgchem.chemmater.kansai-u.ac.jp/index.html

Research fields	keyword
Organic chemistry
Organic chemistry
Organic metalic compound
Industrial organic chemistry
Manufacturing of various organic compounds
Synthetic chemistry

research topic	New anionic NHC ligand design
Study theme state	Individual Research
research duration
Research Programs
keyword	NHC ligand
Research field
Research Topics Overview

research topic	Development of an efficient method for catalytic asymmetric organic reaction
Study theme state	Individual Research
research duration
Research Programs
keyword	Catalytic asymmetric reaction
Research field
Research Topics Overview

research topic	Development of New Reaction by Organometallic Complex
Study theme state	Individual Research
research duration
Research Programs
keyword	Transition metal complex
Research field
Research Topics Overview

所属学会・団体名	役職名 (役職在任期間)
Chemical Society of Japan
The Society of Synthetic Organic Chemistry
The Japan Petroleum Institute	20030401(), 20080401()
The Royal Society of Chemistry
American Chemical Society
Kinki Chemical Society
Catalysis Society of Japan

Research Publications

No.	Type of publication	Date of publication (Date of presentation)	Title	Type of research result	Jointly authored or single authored	Publisher and journal name	Volume number
1	研究紹介99	2013/1/18～2013,01,18,,,	Copper-NHC Complexes for the Asymmetric Addition to Acyclic Enones	Academic Journal	Co-author	Synfacts	9(2), 183
2	International academic conference8	2009/11/10～2009,11,10,,,	Reversal of Enantioselectivity in NHC–Cu Catalyzed Asymmetric Conjugate Addition of Dialkylzinc to Cyclic Enones		Co-author	11th International KYOTO conference on New Aspects of Organic Chemistry (IKCOC-11)
3	Papers1	2009/3/16～2009,03,16,,,	An Air/Water-Stable Tridentate N-Heterocyclic Carbene-Palladium(II) Complex: Catalytic C-H Activation of Hydrocarbons via Hydrogen/Deuterium Exchange Process in Deuterium Oxide	Academic Journal	Co-author	Adv. Synth. Catal.
4	Book2	2009/2～2009,02,00,,,	Iridium-catalyzed coupling reactions	Monograph	Co-author	Wiley-VCH	251-275
5	Papers1	2005/9～2005,09,00,,,	A Remarkable Effect of bases on the Catalytic Radical Addition of Cyanoacetates to Alkenes Using a Mn(II)/Co(II)/O2 Redox System	Academic Journal	Co-author	Bull. Chem. Soc. Jpn.	Vol.78 pp. 1673-1676
6	Papers1	2005/7/8～2005,07,08,,,	Oxidative coupling of Benzenes with a,b-Unsaturated Aldehydes by the Pd(OAc)2/Molybdovanadophosphoric Acid/O2 System	Academic Journal	Co-author	J. Org. Chem	Vol. 70 pp.5471-5474
7	International academic conference8	2005/7/7～2005,07,07,,,	Nitrasation of Cyclohexane Catalyzed by N-Hydroxyputhalimide	Other	Co-author	14th European Symposium on Organic Chemistry (ESOC-14)	381
8	Papers1	2005/7/4～2005,07,04,,,	Synthesis of quinolines from amino alcohol and ketones catalyzed by [IrCl(cod)]2 or IrCl3 under solvent-free conditions	Academic Journal	Co-author	Tetrahedron Lett.
9	Papers1	2005/5/30～2005,05,30,,,	One-pot synthesis of phenol and cyclohexanone from cyclohexylbenzene catalyzed by N-hydroxyphthalimide (NHPI)	Academic Journal	Co-author	Tetrahedron
10	Papers1	2005/5/23～2005,05,23,,,	Synthesis of a-hydroxy-c-butyrolactones from acrylates and 1,3-dioxolanes using N-hydroxyphthalimide (NHPI) as a key catalyst	Academic Journal	Co-author	Tetrahedron Lett.
11	Papers1	2005/5～2005,05,00,,,	Iridium Complex-Catalyzed Cross-Coupling Reaction of Terminal Alkynes with InternalAlkynes via C-H Activation of Terminal Alkynes	Academic Journal	Co-author	Adv. Synth. Catal.
12	Papers1	2005/4/22～2005,04,22,,,	Hydroxylation of Benzene to Phenol under Air and Carbon Monoxide Catalyzed by Molybdovanadophosphoric Acid	Academic Journal	Co-author	Angew. Chem. Int. Ed.
13	Papers1	2005/3/18～2005,03,18,,,	Catalytic Reductive Alkylation of Secondary Amine with Aldehyde and Silane by an Iridium Compound	Academic Journal	Co-author	J. Org. Chem.
14	Papers1	2005/1/28～2005,01,28,,,	Carboxylation of anisole derivatives with CO and O2 catalyzed by Pd(OAc)2 and molybdovanadophosphates	Academic Journal	Co-author	Chem. Commun.
15	International academic conference8	2004/12/14～2004,12,14,,,	Ir-Catalyzed Reductive Alkylation of Amines with Aldehydes and Silane		Co-author	Internatinal Symposium on Catalysis and Fine Chemicals 2004 (C&FC2004)	p.163
16	Papers1	2004/11/5～2004,11,05,,,	Oxidative Cross-Coupling of Acrylates with Vinyl Carboxylates Catalyzed by a Pd(OAc)2/HPMoV/O2 System	Academic Journal	Co-author	Org. Lett.
17	Papers1	2004/11/1～2004,11,01,,,	Development of an efficient method for preparation of 1,3,5-trihydroxyisocyanuric acid (THICA) and its use as aerobic oxidation catalyst	Academic Journal	Co-author	Tetrahedron Lett.
18	Papers1	2004/8/6～2004,08,06,,,	Hydrophosphorylation of Alkenes with Dialkyl Phosphites Catalyzed by Mn(III) under Air	Academic Journal	Co-author	J. Org. Chem.
19	Papers1	2004/7/20～2004,07,20,,,	Iridium-Catalyzed Coupling of Simple Primary or Secondary Amines, Aldehydes and Trimethylsilylacetylene: Preparation of Propargylic Amines	Academic Journal	Co-author	Chem. Commun.
20	International academic conference8	2004/7/6～2004,07,06,,,	Iridium-Catalyzed Coupling of Simple Primaty or Secondary Amines, Aldehydes and Trimethylsilylacetylene: Preparation of Propargylic Amines		Co-author	14th International Symposium on Homogeneous Catalysis Book of Abstracts	p.158
21	Book2	2004/7～2004,07,00,,,	Modern Oxidation Methods	Monograph	Co-author	Wiley-VCH
22	Papers1	2004/5/14～2004,05,14,,,	Allylation of Alcohols and Carboxylic Acids with Allyl Acetate Catalyzed by [ir(cod)2]+BF4- Complex	Academic Journal	Co-author	J. Org. Chem.	Vol. 69, No. 10, p.3474-3477
23	Papers1	2004/5/1～2004,05,01,,,	A Novel Catalysis of [{IrCl(cod)}2] Complex in Organic Syntheses	Academic Journal	Co-author	Bull. Chem. Soc. Jpn.
24	Papers1	2004/2/20～2004,02,20,,,	Pd(OAc)2-Catalyzed Oxidative Coupling reaction of Benzenes with Olefins in the Presence of Molybdovanadophosphoric Acid under Atmospheric Dioxygen and Air	Academic Journal	Co-author	J. Org. Chem.
25	Papers1	2004/2/20～2004,02,20,,,	A New Route to Lactam Precursors from Cycloalkanes: Direct Production of Nitrosocycloalkanes or Cycloalkanone Oximes by Using tert-Butyl Nitrite and N-Hydroxyphthalimide	Academic Journal	Co-author	Angew. Chem. Int. Ed.
26	Papers1	2004/2～2004,02,00,,,	Synthesis of Naphthalenediol by Aerobic Oxidation of Diisopropylnaphthalenes Catalyzed by N-Hydroxyphthalimide(NHPI)/a,a'-Azobisisobutyronitrile(AIBN)	Academic Journal	Co-author	Adv. Synth. Catal.
27	Papers1	2004/1/1～2004,01,01,,,	An Efficien Direct a-Alkylation of Ketones with Primary Alcohols Catalyzed by [Ir(cod)Cl]2/PPh3/KOH System without Solvent	Academic Journal	Co-author	J. Am. Chem. Soc.
28	Papers1	2003/11/1～2003,11,01,,,	Development of Catalytic Carbon Radical Generation and Its Application to Organic Synthesis	Academic Journal	Co-author	J. Synth. Org. Chem. Jpn.
29	International academic conference8	2003/9/14～2003,09,14,,,	Alkylation of Ketones with Alcohols Catalyzed by Iridium Complex		Co-author	13th European Symposium on Organic Chemistry (ESOC 13)	314
30	Papers1	2003/8/22～2003,08,22,,,	Oxidation of substituted toluenes with molecular oxygen in the presence of N,N ',N ''-trihydroxyisocyanuric acid as a key catalyst	Academic Journal	Co-author	J. Org. Chem.	68/17, 6587
31	Papers1	2003/7/25～2003,07,25,,,	Addition of carboxyalkyl radicals to alkenes through a catalytic process, using a Mn(II)/Co(II)/O-2 redox system	Academic Journal	Co-author	J. Org. Chem.	68/15, 5974
32	Papers1	2003/7/21～2003,07,21,,,	Addition of aldehydes and their equivalents to electron-deficient alkenes using N-hydroxyphthalimide (NHPI) as a polarity-reversal catalyst	Academic Journal	Co-author	Tetrahedron Lett.	44/30, 5601
33	Papers1	2003/6/9～2003,06,09,,,	Synthesis of epsilon-caprolactam precursors through the N-hydroxyphthalimide-catalyzed aerobic oxidation of K/A-oil	Academic Journal	Co-author	Green Chem.	5/3, 300
34	Papers1	2003/6～2003,06,00,,,	The first hydroxysilylation of alkenes with triethylsilane under dioxygen catalyzed by N-hydroxyphthalimide	Academic Journal	Co-author	Eur. J. Org. Chem.	12, 2286
35	Papers1	2003/3/3～2003,03,03,,,	Oxidation of nitrotoluenes with air using N-hydroxyphthalimide analogues as key catalysts	Academic Journal	Co-author	Tetrahedron Lett.	44/10, 2053
36	Papers1	2003/2/12～2003,02,12,,,	Direct Coupling of Benzene with Olefin Catalyzed by Pd(OAc)2 Combined with Heteropolyoxometalate Under Dioxygen	Academic Journal	Co-author	J. Am. Chem. Soc.
37	Papers1	2003/2/7～2003,02,07,,,	Head-to-tail dimerization of acrylates catalyzed by iridium complexes	Academic Journal	Co-author	Chem. Commun.
38	International academic conference8	2003/1/9～2003,01,09,,,	Alkane Nitration Assisted by N-Hydroxyphthalimide		Co-author	2003 Gordon Research Conferences on Hydrocarbon Resources, Ventura
39	Papers1	2003/1/1～2003,01,01,,,	Synthesis of enol and vinyl esters catalyzed by an iridium complex	Academic Journal	Co-author	Tetrahedron Lett.
40	Papers1	2003/1～2003,01,00,,,	Oxidation of Unsaturated Hydrocarbons by Pd(OAc)2 Using a Molybdovanadophosphate/Dioxygen System	Academic Journal	Co-author	Journal of the Japan Petroleum Institute
41	Papers1	2002/12/2～2002,12,02,,,	Aerobic oxidation of ethane to acetic acid catalyzed by N,N'-dihydroxypyromellitimide combined with Co species	Academic Journal	Co-author	Tetrahedron Lett.
42	Papers1	2002/12/2～2002,12,02,,,	Selective Wacker-type oxidation of terminal alkenes and dienes using the Pd(II)/molybdovanadophosphate (NPMoV)/O2 system	Academic Journal	Co-author	Tetrahedron Lett.
43	総説99	2002/10～2002,10,00,,,	Discovery of a carbon radical producing catalyst and its application to organic synthesis	Other	Co-author		116, 2-15
44	Papers1	2002/9/15～2002,09,15,,,	Nitration of Alkanes with Nitric Acid Catalyzed by N-Hydroxyphthalimide	Academic Journal	Co-author	Adv. Synth. Catal.
45	International academic conference8	2002/9/6～2002,09,06,,,	Remarkable Effect of Nitrogen Dioxide for N-Hydroxyphthalimide-Catalyzed Aerobic Oxidation of Methylquinolines		Co-author	13th International Symposium on Homogeneous Catalysis (ISHC13), Tarragona	232
46	Papers1	2002/8/9～2002,08,09,,,	An Efficient Nitration of Light Alkanes and the Alkyl Side-Chain of Aromatic Compounds with Nitrogen Dioxide and Nitric Acid Catalyzed by N-Hydroxyphthalimide	Academic Journal	Co-author	J. Org. Chem.
47	International academic conference8	2002/7/15～2002,07,15,,,	First Ritter-type Reaction of Alkylbenzenes Using N-Hydroxyphthalimide		Co-author	14th International Conference on Organic Synthesis (IUPAC/ICOS-14), Christchurch	141
48	Papers1	2002/7/12～2002,07,12,,,	Oxidative Carbomethoxylation of Alkenes Using a Pd(II)/Molybdovanadophosphate (NPMoV) System under Carbon Monoxide and Air	Academic Journal	Co-author	J. Org. Chem.
49	Papers1	2002/5/13～2002,05,13,,,	Radical addition of ethers to alkenes under dioxygen catalyzed by N-hydroxyphthalimide (NHPI)/Co(OAc)2	Academic Journal	Co-author	Tetrahedron Lett.
50	Papers1	2002/2/8～2002,02,08,,,	Catalytic Radical Addition of Carbonyl Compounds to Alkenes by Mn(II)/Co(II)/O2 System	Academic Journal	Co-author	J. Org. Chem.
51	Papers1	2002/2/4～2002,02,04,,,	Development of Highly Efficient Catalytic Method for Synthesis of Vinyl Ethers	Academic Journal	Co-author	J. Am. Chem. Soc.
52	Papers1	2002/2～2002,02,00,,,	First Ritter-type reaction of alkylbenzenes using N-hydroxyphthalimide as a key catalyst	Academic Journal	Co-author	Chem. Commun.
53	Papers1	2002/1/21～2002,01,21,,,	Remarkable effect of nitrogen dioxide for N-hydroxyphthalimide-catalyzed aerobic oxidation of methylquinolines	Academic Journal	Co-author	Chem. Commun.
54	Papers1	2001/12～2001,12,00,,,	Preparation of Hydroperoxides by N-Hydroxyphthalimide-Catalyzed Aerobic Oxidation of Alkylbenzenes and Hydroaromatic Compounds and Its Application	Academic Journal	Co-author	Adv. Synth. Catal.
55	Papers1	2001/11/21～2001,11,21,,,	The radical-chain addition of aldehydes to alkenes by the use of N-hydroxyphthalimide (NHPI) as a polarity-reversal catalyst	Academic Journal	Co-author	Chem. Commun.
56	Papers1	2001/11/16～2001,11,16,,,	Alkane Oxidation with Air Catalyzed by Lipophilic N-Hydroxyphthalimides without Any Solvent	Academic Journal	Co-author	J. Org. Chem.
57	Papers1	2001/9/21～2001,09,21,,,	Catalytic Oxyalkylation of Alkenes with Alkanes and Molecular Oxygen via a Radical Process using N-Hydroxyphthalimide	Academic Journal	Co-author	J. Org. Chem.
58	Papers1	2001/7/20～2001,07,20,,,	Nitration of Alkanes with Nitric Acid Catalyzed by N-Hydroxyphthalimide	Academic Journal	Co-author	Chem. Commun.
59	Papers1	2001/7/2～2001,07,02,,,	A Three- Component Coupling Reaction of Aldehydes, Amines,and Alkynes	Academic Journal	Co-author	Angew. Chem. Int. Ed.
60	Papers1	2001/7～2001,07,00,,,	Innovation of Hydrocarbon Oxidation with Molecular Oxygen and Related Reactions	Academic Journal	Co-author	Adv. Synth. Catal.	343/5, 393-427
61	Papers1	2001/6/29～2001,06,29,,,	Iridium-Catalyzed Transfer Hydrogenation of r,a-Unsaturated and Saturated Carbonyl Compounds with 2-Propanol	Academic Journal	Co-author	J. Org. Chem.
62	Papers1	2001/5/28～2001,05,28,,,	A New Strategy for Catalytic Baeyer-Villiger Oxidation of KA-oil with Molecular Oxygen Using N-Hydroxyphthalimide	Academic Journal	Co-author	Tetrahedron Lett.
63	Papers1	2001/2～2001,02,00,,,	A New Strategy for the Preparation of Terephthalic Acid by the Aerobic Oxidation of p-Xylene using N-Hydroxyphthalimide as a Catalyst	In-house publication	Co-author	Adv. Synth. Catal.
64	Papers1	2001/1/8～2001,01,08,,,	An Efficient Catalytic Alkane Nitration with NO2 under Air Assisted by N-Hydroxyphthalimide	Academic Journal	Co-author	Angew. Chem. Int. Ed.
65	Papers1	2000/12/28～2000,12,28,,,	Rearrangement of Allyl Homoallyl Ethers to g,d-Unsaturated Carbonyl Compounds Catalyzed by Iridium Complexes	Academic Journal	Co-author	Org. Lett.
66	Papers1	2000/12/23～2000,12,23,,,	Reaction of homoallylic alcohols with NaIO4/NaHSO3 reagent - synthesis of alkyl substituted tetrahydrofuran derivatives	Academic Journal	Co-author	Tetrahedron Lett.	41/52, 10223-10227
67	Papers1	2000/12/11～2000,12,11,,,	N-Hydroxyphthalimide-catalyzed radical addition of 1,3-dioxolanes and molecular oxygen to alkenes under ambient conditions: a new route to b-oxycarbonyl compounds	Academic Journal	Co-author	Chem. Commun.
68	Papers1	2000/11/22～2000,11,22,,,	Catalytic radical addition of ketones to alkenes by a metal-dioxygen redox system	Academic Journal	Co-author	Chem. Commum.
69	Papers1	2000/11/17～2000,11,17,,,	Aerobic Oxidation of Methylpyridines to Pyridinecarboxylic Acids Catalyzed by N-Hydroxyphthalimide	Academic Journal	Co-author	Org. Pro. Res. Dev.
70	Papers1	2000/10/9～2000,10,09,,,	Efficient oxidation of alcohols to Carbonyl Compounds with Molecular Oxygen Catalyzed by N-hydroxyphthalimide Combined with a Co Species	Academic Journal	Co-author	J. Org. Chem.
71	Papers1	2000/9/22～2000,09,22,,,	An Efficient Synthesis of Dinitrule Derivatives by the Reaction of Oxime Ester or Acid Anhydrides with Cyanotrimethylsilane Catalyzed by La(OiPr)3	Academic Journal	Co-author	J. Org. Chem.
72	Papers1	2000/8/2～2000,08,02,,,	The First Catalytic Sulfoxidation of Saturated Hydrocarbons with SO2/O2 by a Vanadium Species	Academic Journal	Co-author	J. Am. Chem. Soc.
73	Papers1	2000/4/29～2000,04,29,,,	Synthesis of 1,3-oxazolidines from imines and epoxides catalyzed by samarium compounds	Academic Journal	Co-author	Tetrahedron Lett.
74	Papers1	2000/3/28～2000,03,28,,,	Catalytic α-hydroxy carbon radical generation and addition. Synthesis of α-hydroxy-γ-lactones from alcohols, α,β-unsaturated esters and dioxygen	Academic Journal	Co-author	Chem. Commum.
75	Papers1	2000/3/28～2000,03,28,,,	Iridium-catalyzed aziridination of aliphatic aldehyde, aliphatic amine and ethyl diazoacetate	Academic Journal	Co-author	Chem. Commum.
76	Papers1	2000/3/4～2000,03,04,,,	Meerwein-Ponndorf-Verley-type reductive acetylation of carbonyl compounds to acetates by lanthanide complexes in the presence of isopropenyl acetate	Academic Journal	Co-author	Tetrahedron Lett.
77	Papers1	2000/3/3～2000,03,03,,,	Production of Hydrogen Peroxide via Aerobic Oxidation of Alcohols Catalyzed by N-Hydroxyphthalimide	Academic Journal	Co-author	Org. Pro. Res. Dev.
78	Papers1	2000/2/24～2000,02,24,,,	Acetalization of Alkenes Catalyzed by Pd(OAc)2/NPMoV Supported on Activated Carbon under a Dioxygen Atmosphere	Academic Journal	Co-author	Org. Lett.
79	Papers1	2000/2/22～2000,02,22,,,	Epoxidation of alkenes with H2O2 generated in situ from alcohols and molecular oxygen using N-hydroxyphthalimide and hexafluoroacetone as catalyst	Academic Journal	Co-author	Heterocycles
80	Papers1	2000/1/17～2000,01,17,,,	Epoxidation of alkenes using alkyl hydroperoxides generated in situ by catalytic autoxidation of hydrocarbons with dioxygen	Academic Journal	Co-author	Chem. Commum.
81	Papers1	2000/1/1～2000,01,01,,,	Wacker-Type Oxidation of Cyclopentene under Dioxygen Atmosphere Catalyzed by Pd(OAc)2/NPMoV on Activated Carbon	Academic Journal	Co-author	Tetrahedron Lett.
82	Papers1	1999/12/3～1999,12,03,,,	Regioselective Synthesis of Alkylpyrroles from Imines and Nitroalkenes by Lanthanide Compounds	Academic Journal	Co-author	Tetrahedron
83	Papers1	1999/9/9～1999,09,09,,,	Oxidative Cleavage of vic-Diols to Aldehyde with Dioxygen Catalyzed by Ru(PPh3)3Cl2 on Active Carvon	Academic Journal	Co-author	Org. Lett.
84	Papers1	1999/8/6～1999,08,06,,,	Dehomologation OF Aldehydes via Oxidative Cleavage of Silyl Enol Ethers with Aqueous Hydrogen Peroxide Catalyzed by Cetylpyridinium Peroxotungstophosphate(PCWP)under Two-Phase Conditions	Academic Journal	Co-author	J. Org. Chem.
85	Papers1	1999/7/20～1999,07,20,,,	Catalytic Redical Acetylation of Adamantanes with Biacetyl by a Cobalt Salt Under Armospheric Dioxygen	Academic Journal	Co-author	Chem. Commum.
86	Papers1	1999/6/25～1999,06,25,,,	A New Approach for Oxygenation Using Nitric Oxide under the Influence of N-Hydroxyphthalimide	Academic Journal	Co-author	J. Org. Chem.
87	Papers1	1999/5/28～1999,05,28,,,	Acetylcyanation of Aldehydes with Acetone Cyanohydrin and Isopropenyl Acetate by Cp*2Sm(thf)2	Academic Journal	Co-author	J. Org. Chem.
88	Papers1	1999/4/13～1999,04,13,,,	Epoxidation of Alkenes Using Dioxygen in the Presence of An Alcohol Catalyzed By N-Hydroxyphthalimide and Hexafluoroacetone without Any Metal Catalyst	Academic Journal	Co-author	Chem. Commum.
89	Papers1	1999/3～1999,03,00,,,	A New Strategy for Alkane Oxidation with O2 using N-Hydroxyphthalimide(NHPI)As a Radical Catalyst	Academic Journal	Co-author	Catalysis Surveys from Japan
90	Papers1	1999/2/8～1999,02,08,,,	A Remarkable Effect of Quaternary Ammonium Bromide for the N-Hydroxyphthalimide-Catalyzed Aerobic Oxidation of Hydrocarbons	Academic Journal	Co-author	Tetrahedron Lett.
91	Papers1	1999/1/25～1999,01,25,,,	Carbonylation of Terminal Alkynes Using a Multicatalytic System, Pb(Ⅱ)Chlorohydroquinone/NPMoV, under Cerbon Monoxide and Dioxygen	Academic Journal	Co-author	Tetrahedron Lett.
92	Papers1	1998/11/2～1998,11,02,,,	Selective Oxidation of Sulfides to Sulfoxides with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide(NHPI)in the Presence of Alcohols	Academic Journal	Co-author	Tetrahedron Lett.
93	Papers1	1998/9/17～1998,09,17,,,	Trimerization of Aliphatic Aldehydes to1,3-Diol Monoesters Catalyzed by Cp*2Sm(thf)2	Academic Journal	Co-author	Tetrahedron Lett.
94	Papers1	1998/9/15～1998,09,15,,,	Oxgenation of Alkynes to α, β-Acetylenic Ketones with Dioxygen Catalyzed by N-Hydroxyphthalimide Combined with a Transition Metal	Academic Journal	Co-author	Chem. Commum.
95	Papers1	1998/9/4～1998,09,04,,,	Preparation of Substituted Alkylpyrroles via Samarium-Catalyzed Three-Component Coupling Reaction of Aldehydes, Amines, and Nitroalkanes	Academic Journal	Co-author	J. Org. Chem.
96	Papers1	1998/8/21～1998,08,21,,,	An Alternative Method for the Selective Bromination of Alkylbenzenes Using NaBrO3/NaHSO3 Reagent	Academic Journal	Co-author	J. Org. Chem.
97	Papers1	1998/7/30～1998,07,30,,,	Selective Aerobic Oxidation of Primary Alcohols Catalyzed by a Ru(PPh3)3Cl2/Hydroquinone System	Academic Journal	Co-author	Tetrahedron Lett.
98	Papers1	1998/7/17～1998,07,17,,,	Direct Conversion of Cyclohexane into Adipic Acid with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide Combined with Mn(acac)2 and Co(OAc)2	Academic Journal	Co-author	Org. Pro. Res. Dev.
99	Papers1	1998/5/15～1998,05,15,,,	An Efficient Aerobic Oxidation of Isobutane to t-Butyl Alcohol by N-Hydroxyphthalimide Combined with Co(II)Species	Academic Journal	Co-author	Bull. Chem. Soc. Jpn.
100	Patents99	1998/3/25～1998,03,25,,,	Production of Nitro Compounds		Co-author
101	Papers1	1998/1/23～1998,01,23,,,	N-Hydroxyphthalimide(NHPI)-Catalyzed Carboxylation of Polycyclic Alkanes with Carbon Monoxide in the Presence of Dioxygen	Academic Journal	Co-author	J. Org. Chem.
102	Papers1	1998/1/5～1998,01,05,,,	A Novel Synthesis of 1,3-Diol Diesters by the Reaction of Aldehydes with Oxime Esters Catalyzed by Samarium Complex	Academic Journal	Co-author	Chem. Lett.
103	Papers1	1997/11/14～1997,11,14,,,	An Efficient Acylation of tert-Alcohols with Isopropenyl Acetate Mediated by an Oxime Ester and Cp*Sm(thf)2	Academic Journal	Co-author	J. Org. Chem.
104	Papers1	1997/10/17～1997,10,17,,,	Slective Oxidation of Vinyl Ethers and Silyl Enol Ethers with Hydrogen Peroxide Catalyzed by Peroxotungstophosphate(PCWP)	Academic Journal	Co-author	J. Org. Chem.
105	Papers1	1997/10/15～1997,10,15,,,	Oxidation of Diols and Ethers by NaBrO3/NaHSO3 Reagent	Academic Journal	Co-author	Bull. Chem. Soc. Jpn.
106	Papers1	1997/10/6～1997,10,06,,,	N-Hydroxyphthalimide(NHPI)-Catalyzed Reaction of Adamantane Under Nitric Oxide Atmosphere	Academic Journal	Co-author	Tetrahedron Lett.
107	Papers1	1997/10/3～1997,10,03,,,	Catalytic Oxidation of Alkylbenzenes with Molecular Oxygen under Normal Pressure and Temperature by N-Hydroxyphthalimide(NHPI)Combined with Co(OAc)2	Academic Journal	Co-author	J. Org. Chem.
108	Papers1	1997/8/27～1997,08,27,,,	Selective Aerobic Oxidation of Isophorone Catalyzed by Molybdovanadophosphate Supported on Carbon(NPMoV/C)	Academic Journal	Co-author	Tetrahedron Lett.
109	Papers1	1997/6/2～1997,06,02,,,	Cyclotrimerization of Alkynes Using a Multicatalytic System, Pd(II)/Chlorohydroquinone/NPMoV, under Dioxygen	Academic Journal	Co-author	Tetrahedron Lett.
110	Papers1	1997/5/16～1997,05,16,,,	Stereoselective Reduction of β-Hydroxy Ketones with Aldehydes via Tishchenko Reactions Catalyzed by Zirconocene Complexes	Academic Journal	Co-author	J. Org. Chem.
111	Papers1	1997～1997,00,00,,,	Development of New Synthetic Reactions Using Samarium Compounds as Catalysts	Monograph	Co-author	Reviews on Heteroatom Chemistry(MYU)
112	Papers1	1996/12/23～1996,12,23,,,	Molybdovanadophosphate(NPMoV)/hydroquinone/O2 system as an efficient reoxidation system in palladium-catalyzed oxidation of alkenes	Academic Journal	Co-author	J. Mol. Cat. A: Chem.
113	Papers1	1996/9/30～1996,09,30,,,	Aldol Type Condensation of Imines Catalyzed by Samarium Complexes	Academic Journal	Co-author	Tetrahedron Lett.
114	Papers1	1996/8/10～1996,08,10,,,	An efficient aerobic oxidation of various organic compounds catalyzed by mixed addenda heteropolyoxometalates containing molybdenum and vanadium	Academic Journal	Co-author	J. Mol. Cat. A: Chem.
115	Papers1	1996/8/9～1996,08,09,,,	Selective Oxidation of Monoterpenes with Hydrogen Peroxide Catalyzed by Peroxotungstophosphate(PCWP)	Academic Journal	Co-author	J. Org. Chem.
116	Papers1	1996/7/12～1996,07,12,,,	Alkane Oxidetion with Molecular Oxygen Vsing a New Efficient Catalytic System:N-Hydroxyphthalimide (NHPI) Combined with Co(acac)n (n=2or3)	Academic Journal	Co-author	J. Org. Chem.
117	Papers1	1996/7/8～1996,07,08,,,	Hydroxylation of Polycyclic Alkanes with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide (NHPI) Combined with Transition Metal Salts	Academic Journal	Co-author	Tetrahedron Lett.
118	Papers1	1996/3/22～1996,03,22,,,	Acylation of Alcohols and Amines with Vinyl Acetates Catalyzed by Cp*2Sm(thf)2	Academic Journal	Co-author	J. Org. Chem.
119	Papers1	1996/3/20～1996,03,20,,,	Oxidation of Organic Substrates with Molecular Oxygen Catalyzed by Vanadomolybdophosphate (NPV6Mo6) Combined with N-Hydroxyphthalimide (NHPI)	Academic Journal	Co-author	Technology Reports of Kansai University,
120	Papers1	1995/10～1995,10,00,,,	Oxidative Esterification of Primary Alcohols by NaBrO3/NaHSO3 Reagent in Aqueous Medium	Academic Journal	Co-author	Chem. Lett.
121	Papers1	1995/9/18～1995,09,18,,,	Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by N-Hydroxyphthalimide (NHPI) Combined	Academic Journal	Co-author	Tetrahedron Lett.
122	Papers1	1995/8/11～1995,08,11,,,	A New Coupling Reaction of Vinyl Esters with Aldehydes Catalyzed by Organosamarium Compounds	Academic Journal	Co-author	J. Org. Chem.
123	Papers1	1995/6/30～1995,06,30,,,	A Novel Catalysis of N-Hydroxyphthalimide in the Oxidation of Organic Substrates by Molecular Oxygen	Academic Journal	Co-author	J. Org. Chem.
124	Papers1	1995/2/27～1995,02,27,,,	A Direct Conversion of vic-Diols into 1,2-Diketones with Agueous Hydrogen Peroxide Catalyzed by Peroxotungstophosphate(PCWP)	Academic Journal	Co-author	Tetrahedron Lett.
125	Papers1	1994/9/23～1994,09,23,,,	Oxidation of Allenes and Alkynes with Hydrogen Peroxide Catalyzed by Cetylpyridinium Peroxotungstophosphate(PCWP)	Academic Journal	Co-author	J. Org. Chem.

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PapersIn refereedAcademic JournalCo-author929, 1215562020/10/7～10.1016/j.jorganchem.2020.121556

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PapersIn refereedAcademic JournalCo-authored876,407-4162017/10/1～10.1016/j.jorganchem.2017.07.025

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PapersIn refereedAcademic JournalCo-author421, 138-1452016/9/10～10.1016/j.molcata.2016.05.020

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PapersIn refereedAcademic JournalCo-author6, 7755-77592016/1/19～10.1039/c5ra25926f

CommentaryIn refereedAcademic JournalSingle-Author3, 80-822015/12/10～

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PapersIn refereedAcademic JournalCo-authorKAMIHIGASHI,Shun;SHIBATA,Naoaya;SAKAGUCHI,Satoshi25, 2933-29372014/12/15～10.1055/s-0034-1378916

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PapersIn refereedAcademic JournalCo-author395, 66-712014/8/10～10.1016/j.molcata.2014.08.006

PapersIn refereedAcademic JournalCo-author5532–55392014/7/23～10.1002/ejoc.201402279

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展示会Single-AuthorSAKAGUCHI,SatoshiＬ-492013/8/30～

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総説In refereedAcademic JournalSingle-AuthorSAKAGUCHI,Satoshi71（4）, 46-552013/4/1～

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研究紹介Copper-NHC Complexes for the Asymmetric Addition to Acyclic EnonesAcademic JournalCo-authorSynfacts9(2), 1832013/1/18～10.1055/s-0032-1317978

PapersIn refereedAcademic JournalCo-author2012/12/4～10.1002/ejoc.201201082

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PapersIn refereedAcademic JournalCo-author696(9), 1910-19152011/5/1～10.1016/j.jourganchem.2011.02.009

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International academic conferenceReversal of Enantioselectivity in NHC–Cu Catalyzed Asymmetric Conjugate Addition of Dialkylzinc to Cyclic EnonesCo-authorSatoshi Sakaguchi;Masaki Okamoto;Yuko Yamamoto11th International KYOTO conference on New Aspects of Organic Chemistry (IKCOC-11)2009/11/10～

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Academic presentationCo-authorSatoshi Sakaguchi;Yuuki Shimakawa;Takashi Morikawa4G1-312009/3/30～

PapersAn Air/Water-Stable Tridentate N-Heterocyclic Carbene-Palladium(II) Complex: Catalytic C-H Activation of Hydrocarbons via Hydrogen/Deuterium Exchange Process in Deuterium OxideIn refereedAcademic JournalCo-authorAdv. Synth. Catal.2009/3/16～

BookIridium-catalyzed coupling reactionsUnrefereedMonographCo-authorWiley-VCH251-2752009/2～

PapersIn refereedAcademic JournalCo-authorAngew. Chem. Int. Ed.2008/11/17～

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International academic conferenceCo-author42nd Western Regional Meeting of the American Chemical SocietyWRM-2112008/9/25～

International academic conferenceCo-author16th International Symposium on Homogeneous Catalysis (ISHC-16)P0792008/7/10～

Magazine articleUnrefereedAcademic JournalSingle-AuthorSatoshi Sakaguchi2008/7/1～

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Research reportUnrefereedIn-house publicationSingle-AuthorSatoshi Sakaguchi2008/3/31～

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Magazine articleUnrefereedAcademic JournalSingle-AuthorSatoshi Sakaguchi2008/3/20～

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International academic conferenceCo-authorInternational Conference on Organic Synthesis (BOS 2006)P0872006/6/26～

PapersIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;T. Mizuta;Y. Ishii2006/6/8～Grant-in-Aid for Encouragement of Young Scientists 20050401-20050331

International academic conferenceCo-author8th International Symposium on Organic Reactions (ISOR-2006)P162006/4/25～

International academic conferenceCo-author8th International Symposium on Organic Reactions (ISOR-2006)P442006/4/25～

PapersIn refereedAcademic JournalCo-author2006/3/13～

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PapersA Remarkable Effect of bases on the Catalytic Radical Addition of Cyanoacetates to Alkenes Using a Mn(II)/Co(II)/O2 Redox SystemIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takashi Kagayama;Takahiro Fuke;Yasutaka IshiiBull. Chem. Soc. Jpn.Vol.78 pp. 1673-16762005/9～Grant-in-Aid for Scientific Research

LectureOtherSingle-AuthorSAKAGUCHI,Satoshi2005/7/29～

PapersOxidative coupling of Benzenes with a,b-Unsaturated Aldehydes by the Pd(OAc)2/Molybdovanadophosphoric Acid/O2 SystemIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Tomoyuki Yamada;Yasutaka IshiiJ. Org. ChemVol. 70 pp.5471-54742005/7/8～Grant-in-Aid for Scientific Research

International academic conferenceNitrasation of Cyclohexane Catalyzed by N-HydroxyputhalimideOtherCo-authorSAKAGUCHI Satoshi;Masaharu Hashimoto;Yasutaka Ishii14th European Symposium on Organic Chemistry (ESOC-14)3812005/7/7～14th European symposium on Organic Chemistry Helsinki

PapersSynthesis of quinolines from amino alcohol and ketones catalyzed by [IrCl(cod)]2 or IrCl3 under solvent-free conditionsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Kazuhiko Taguchi;Yasutaka IshiiTetrahedron Lett.2005/7/4～Grant-in-Aid for Encouragement of Young Scientists

PapersOne-pot synthesis of phenol and cyclohexanone from cyclohexylbenzene catalyzed by N-hydroxyphthalimide (NHPI)In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasuhiro Aoki;Yasutaka IshiiTetrahedron2005/5/30～

PapersSynthesis of a-hydroxy-c-butyrolactones from acrylates and 1,3-dioxolanes using N-hydroxyphthalimide (NHPI) as a key catalystIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takashi Kagayama;Yasutaka IshiiTetrahedron Lett.2005/5/23～

PapersIridium Complex-Catalyzed Cross-Coupling Reaction of Terminal Alkynes with InternalAlkynes via C-H Activation of Terminal AlkynesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Tomotaka Hirabayashi;Yasutaka IshiiAdv. Synth. Catal.2005/5～

PapersHydroxylation of Benzene to Phenol under Air and Carbon Monoxide Catalyzed by Molybdovanadophosphoric AcidIn refereedAcademic JournalCo-authorAngew. Chem. Int. Ed.2005/4/22～

PapersCatalytic Reductive Alkylation of Secondary Amine with Aldehyde and Silane by an Iridium CompoundIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Tomoya Mizuta;Yasutaka IshiiJ. Org. Chem.2005/3/18～

PapersCarboxylation of anisole derivatives with CO and O2 catalyzed by Pd(OAc)2 and molybdovanadophosphatesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Shinichiro Ohhashi;Yasutaka IshiiChem. Commun.2005/1/28～

PapersIn refereedAcademic JournalCo-author2005～Grant-in-Aid for Encouragement of Young Scientists

International academic conferenceIr-Catalyzed Reductive Alkylation of Amines with Aldehydes and SilaneCo-authorSAKAGUCHI Satoshi;Tomoya Mizuta;Yasutaka IshiiInternatinal Symposium on Catalysis and Fine Chemicals 2004 (C&FC2004)p.1632004/12/14～Internatinal Symposium on Catalysis and Fine Chemicals 2004 Hong Kong

PapersOxidative Cross-Coupling of Acrylates with Vinyl Carboxylates Catalyzed by a Pd(OAc)2/HPMoV/O2 SystemIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yuji Hatamoto;Yasutaka IshiiOrg. Lett.2004/11/5～

PapersDevelopment of an efficient method for preparation of 1,3,5-trihydroxyisocyanuric acid (THICA) and its use as aerobic oxidation catalystIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Naruhisa Hirai;Takashi Kagawama;Yoshinobu Tatukawa;Yasutaka IshiiTetrahedron Lett.2004/11/1～

PapersHydrophosphorylation of Alkenes with Dialkyl Phosphites Catalyzed by Mn(III) under AirIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Osamu Tayama;Atushi Nakano;Takahiro Iwahama;Yasutaka IshiiJ. Org. Chem.2004/8/6～

BookIn refereedMonographCo-author2004/7/30～

PapersIridium-Catalyzed Coupling of Simple Primary or Secondary Amines, Aldehydes and Trimethylsilylacetylene: Preparation of Propargylic AminesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;T.Mizuta;M.Furuwan;T.Kubo;Y.IshiiChem. Commun.2004/7/20～

International academic conferenceIridium-Catalyzed Coupling of Simple Primaty or Secondary Amines, Aldehydes and Trimethylsilylacetylene: Preparation of Propargylic AminesCo-authorSAKAGUCHI Satoshi;Tomoya Mizuta;Yasutaka Ishii14th International Symposium on Homogeneous Catalysis Book of Abstractsp.1582004/7/6～14th International Symposium on Homogeneous Catalysis, Munich Germany

BookModern Oxidation MethodsUnrefereedMonographCo-authorSAKAGUCHI Satoshi;Yasutaka IshiiWiley-VCH2004/7～

PapersAllylation of Alcohols and Carboxylic Acids with Allyl Acetate Catalyzed by [ir(cod)2]+BF4- ComplexIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Hideto Nakagawa;Tomotaka Hirabayashi;Yasutaka IshiiJ. Org. Chem.Vol. 69, No. 10, p.3474-34772004/5/14～

PapersA Novel Catalysis of [{IrCl(cod)}2] Complex in Organic SynthesesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka IshiiBull. Chem. Soc. Jpn.2004/5/1～

BookUnrefereedMonographCo-author2004/3/25～

PapersPd(OAc)2-Catalyzed Oxidative Coupling reaction of Benzenes with Olefins in the Presence of Molybdovanadophosphoric Acid under Atmospheric Dioxygen and AirIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;M.Tani;Y.IshiiJ. Org. Chem.2004/2/20～

PapersA New Route to Lactam Precursors from Cycloalkanes: Direct Production of Nitrosocycloalkanes or Cycloalkanone Oximes by Using tert-Butyl Nitrite and N-HydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;T.Hirabayashi;Y.IshiiAngew. Chem. Int. Ed.2004/2/20～

PapersSynthesis of Naphthalenediol by Aerobic Oxidation of Diisopropylnaphthalenes Catalyzed by N-Hydroxyphthalimide(NHPI)/a,a'-Azobisisobutyronitrile(AIBN)In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasuhiro Aoki;Yasutaka IshiiAdv. Synth. Catal.2004/2～

PapersAn Efficien Direct a-Alkylation of Ketones with Primary Alcohols Catalyzed by [Ir(cod)Cl]2/PPh3/KOH System without SolventIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;K.Taguchi;H.Nakagawa;T.Hirabayashi;Y.IshiiJ. Am. Chem. Soc.2004/1/1～

PapersDevelopment of Catalytic Carbon Radical Generation and Its Application to Organic SynthesisIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka IshiiJ. Synth. Org. Chem. Jpn.2003/11/1～

International academic conferenceAlkylation of Ketones with Alcohols Catalyzed by Iridium ComplexIn refereedCo-author13th European Symposium on Organic Chemistry (ESOC 13)3142003/9/14～13th European Symposium on Organic ChemistryGrant-in-Aid for Encouragement of Young Scientists

PapersOxidation of substituted toluenes with molecular oxygen in the presence of N,N ',N ''-trihydroxyisocyanuric acid as a key catalystIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;N.Hirai;Naoko Sawakari;Norihiro Nakamura;Yasutaka IshiiJ. Org. Chem.68/17, 65872003/8/22～N,N',N”-Trihydroxyisocianuric acid (THICA) was found to be a very efficient catalyst for the oxidation of alkylbenzenes with dioxygen. Thus, a variety of meta- and para-substituted toluenes bearing an electron-withdrawing substituent such as cyanotoluene, chlorotoluene, and toluic acid under O-2 (1 atm) in the presence of THICA (5 mol %) and Co(OAc)(2) (0.5 mol %) at 100 degreesC were smoothly oxidized to the corresponding benzoic acids in almost quantitative yields. The aerobic oxidation of toluene by THICA was compared with that by N-hydroxyphthalimide. p-Xylene was efficiently oxidized by THICA to telephthalic acid in high yield (over 95%) under mild conditions.

PapersAddition of carboxyalkyl radicals to alkenes through a catalytic process, using a Mn(II)/Co(II)/O-2 redox systemIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Kouji Hirase;Yasutaka IshiiJ. Org. Chem.68/15, 59742003/7/25～A novel strategy for production of mono- and dicarboxylic acids by the addition of carboxyalkyl radicals to alkenes and dienes, respectively, was successfully developed through a catalytic process with use of Mn(II)/CO(II)/O-2 system. Thus, a variety of carboxylic acids were prepared by the reaction of alkenes and dienes with acid anhydrides in the presence of a very small amount of Mn(OAc)(2) (0.5 mol %) and Co(OAc)(2) (0.1 mol %) under dilute dioxygen.

PapersAddition of aldehydes and their equivalents to electron-deficient alkenes using N-hydroxyphthalimide (NHPI) as a polarity-reversal catalystIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Shinya Tsujimoto;Yasutaka IshiiTetrahedron Lett.44/30, 56012003/7/21～Radical addition of aldehydes and masked aldehydes like 1,3-dioxolanes to electron-deficient alkenes was achieved by the use of catalytic amounts of BPO and N-hydroxyphthalimide (NHPI) as a polarity-reversal catalyst under mild conditions. Three-component radical coupling of 1,3-dioxolanes, maleates, and alkenes was performed in the presence of BPO and NHPI under similar conditions.

PapersSynthesis of epsilon-caprolactam precursors through the N-hydroxyphthalimide-catalyzed aerobic oxidation of K/A-oilIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Shigeru Yamamoto;Yasutaka IshiiGreen Chem.5/3, 3002003/6/9～A methodology for the preparation of e-caprolactam (CL) precursors like 1,1'-peroxydicyclohexylamine (PDHA) and/or cyclohexanone oxime from K/A-oil (a mixture of cyclohexanone and cyclohexanol) has been established by the use of N-hydroxyphthalimide (NHPI) as a key catalyst. Thus, the aerobic oxidation of K/A-oil catalyzed by NHPI followed by treatment with ammonia afforded CL precursors in high selectivities.

PapersThe first hydroxysilylation of alkenes with triethylsilane under dioxygen catalyzed by N-hydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Osamu Tayama;Takahiro Iwahama;Yasutaka IshiiEur. J. Org. Chem.12, 22862003/6～Catalytic hydroxysilylation of alkenes with trialkylsilane under dioxygen through a radical process was successfully achieved by the use of N-hydroxyphthalimide (NHPI) as a catalyst under mild conditions.

PapersOxidation of nitrotoluenes with air using N-hydroxyphthalimide analogues as key catalystsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Naoko Sawatari;Yasutaka IshiiTetrahedron Lett.44/10, 20532003/3/3～Nitrotoluenes are efficiently oxidized with air to the corresponding nitrobenzoic acids by the use of N-acetoxyphthalimide (NAPI) as a key catalyst. Thus, p- and m-nitrotoluenes under 10 atm of air in the presence of NAPI combined with Co(OAC)2 (0.5 mol%) and Mn(OAc)(2) (0.05 mol%) at 130degreesC afforded p- and m-nitrobenzoic acids in 81 and 92% yields, respectively. o-Nitrotoluene was oxidized to o-nitrobenzoic acid in 51% yield by the aid of NO2.

PapersDirect Coupling of Benzene with Olefin Catalyzed by Pd(OAc)2 Combined with Heteropolyoxometalate Under DioxygenIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Yokota;Masayuki Tani;Yasutaka IshiiJ. Am. Chem. Soc.2003/2/12～

PapersHead-to-tail dimerization of acrylates catalyzed by iridium complexesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Hideto Nakagawa;Yasutaka IshiiChem. Commun.2003/2/7～Head-to-tail dimerizations of acrylates and vinyl ketone were successfully performed by the use of iridium complexes in good yields. An iridium hydride complex generated in situ from [IrCl(cod)](2) and alcohols in the presence of Na2CO3 and (MeO)(3)P was found to be an active species promoting the head-to-tail dimerization of acrylates. Thus, butyl acrylate afforded the corresponding head-to-tail dimer in 86% yield.

International academic conferenceAlkane Nitration Assisted by N-HydroxyphthalimideCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii2003 Gordon Research Conferences on Hydrocarbon Resources, Ventura2003/1/9～2003 Gordon Research Conferences on Hydrocarbon Resources

PapersSynthesis of enol and vinyl esters catalyzed by an iridium complexIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Hideto Nakagawa;Yasutaka IshiiTetrahedron Lett.2003/1/1～

PapersOxidation of Unsaturated Hydrocarbons by Pd(OAc)2 Using a Molybdovanadophosphate/Dioxygen SystemIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Yokota;Yasutaka IshiiJournal of the Japan Petroleum Institute2003/1～

総説UnrefereedAcademic JournalCo-author2003～

PapersAerobic oxidation of ethane to acetic acid catalyzed by N,N'-dihydroxypyromellitimide combined with Co speciesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Akihiro Shibamoto;Yasutaka IshiiTetrahedron Lett.2002/12/2～

PapersSelective Wacker-type oxidation of terminal alkenes and dienes using the Pd(II)/molybdovanadophosphate (NPMoV)/O2 systemIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Yokota;Aki Sakakura;Masayuki Tani;Yasutaka IshiiTetrahedron Lett.2002/12/2～

総説UnrefereedAcademic JournalCo-author2002/12/1～

CommentaryUnrefereedAcademic JournalCo-author2002/11/1～

総説UnrefereedOtherCo-author2002/10～

総説Discovery of a carbon radical producing catalyst and its application to organic synthesisOtherCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii116, 2-152002/10～

PapersNitration of Alkanes with Nitric Acid Catalyzed by N-HydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Shinji Isozaki;Yoshiki Nishiwaki;Yasutaka IshiiAdv. Synth. Catal.2002/9/15～

International academic conferenceRemarkable Effect of Nitrogen Dioxide for N-Hydroxyphthalimide-Catalyzed Aerobic Oxidation of MethylquinolinesUnrefereedCo-authorSAKAGUCHI Satoshi;Akihiro Shibamoto;Yasutaka Ishii13th International Symposium on Homogeneous Catalysis (ISHC13), Tarragona2322002/9/6～ISHC-13

PapersAn Efficient Nitration of Light Alkanes and the Alkyl Side-Chain of Aromatic Compounds with Nitrogen Dioxide and Nitric Acid Catalyzed by N-HydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yoshiki Nishiwaki;Yasutaka IshiiJ. Org. Chem.2002/8/9～

International academic conferenceFirst Ritter-type Reaction of Alkylbenzenes Using N-HydroxyphthalimideUnrefereedCo-author14th International Conference on Organic Synthesis (IUPAC/ICOS-14), Christchurch1412002/7/15～14th International Conference on Organic Synthesis (IUPAC/ICOS-14)

PapersOxidative Carbomethoxylation of Alkenes Using a Pd(II)/Molybdovanadophosphate (NPMoV) System under Carbon Monoxide and AirIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Yokota;Yasutaka IshiiJ. Org. Chem.2002/7/12～

PapersRadical addition of ethers to alkenes under dioxygen catalyzed by N-hydroxyphthalimide (NHPI)/Co(OAc)2In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Kazutaka Hirano;Yasutaka IshiiTetrahedron Lett.2002/5/13～

総説UnrefereedIn-house publicationCo-author2002/3～

PapersCatalytic Radical Addition of Carbonyl Compounds to Alkenes by Mn(II)/Co(II)/O2 SystemIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Kouji Hirase;Takahiro Iwahama;Yasutaka IshiiJ. Org. Chem.2002/2/8～

PapersDevelopment of Highly Efficient Catalytic Method for Synthesis of Vinyl EthersIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yoshio Okimoto;Yasutaka IshiiJ. Am. Chem. Soc.2002/2/4～

PapersFirst Ritter-type reaction of alkylbenzenes using N-hydroxyphthalimide as a key catalystIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Tomotaka Hirabayashi;Yasutaka IshiiChem. Commun.2002/2～

PapersRemarkable effect of nitrogen dioxide for N-hydroxyphthalimide-catalyzed aerobic oxidation of methylquinolinesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Akihiro Shibamoto;Yasutaka IshiiChem. Commun.2002/1/21～

CommentaryUnrefereedAcademic JournalCo-author2001/12/6～

PapersPreparation of Hydroperoxides by N-Hydroxyphthalimide-Catalyzed Aerobic Oxidation of Alkylbenzenes and Hydroaromatic Compounds and Its ApplicationIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Osamu Fukuda;Yasutaka IshiiAdv. Synth. Catal.2001/12～

PapersThe radical-chain addition of aldehydes to alkenes by the use of N-hydroxyphthalimide (NHPI) as a polarity-reversal catalystIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Shinya Tsujimoto;Takahiro Iwahama;Yasutaka IshiiChem. Commun.2001/11/21～

PapersAlkane Oxidation with Air Catalyzed by Lipophilic N-Hydroxyphthalimides without Any SolventIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Naoko Sawatari;Takahiro Yokota;Yasutaka IshiiJ. Org. Chem.2001/11/16～

PapersCatalytic Oxyalkylation of Alkenes with Alkanes and Molecular Oxygen via a Radical Process using N-HydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takafumi Hara;Takahiro Iwahama;Yasutaka IshiiJ. Org. Chem.2001/9/21～

PapersA Three- Component Coupling Reaction of Aldehydes, Amines,and AlkynesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takashi Kubo;Yasutaka IshiiAngew. Chem. Int. Ed.2001/7/2～

PapersInnovation of Hydrocarbon Oxidation with Molecular Oxygen and Related ReactionsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro IwahamaAdv. Synth. Catal.343/5, 393-4272001/7～

PapersIridium-Catalyzed Transfer Hydrogenation of r,a-Unsaturated and Saturated Carbonyl Compounds with 2-PropanolIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takumi Yamaga;Yasutaka IshiiJ. Org. Chem.2001/6/29～

PapersA New Strategy for Catalytic Baeyer-Villiger Oxidation of KA-oil with Molecular Oxygen Using N-HydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Osamu Fukuda;Yasutaka IshiiTetrahedron Lett.2001/5/28～

PapersA New Strategy for the Preparation of Terephthalic Acid by the Aerobic Oxidation of p-Xylene using N-Hydroxyphthalimide as a CatalystIn refereedIn-house publicationCo-authorSAKAGUCHI Satoshi;Yasutaka Tashiro;Takahiro Iwahama;Yasutaka IshiiAdv. Synth. Catal.2001/2～

PapersAn Efficient Catalytic Alkane Nitration with NO2 under Air Assisted by N-HydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yoshiki Nishiwaki;Takaaki Kitamura;Yasutaka IshiiAngew. Chem. Int. Ed.2001/1/8～

総説In refereedAcademic JournalCo-author2001/1/1～

PapersRearrangement of Allyl Homoallyl Ethers to g,d-Unsaturated Carbonyl Compounds Catalyzed by Iridium ComplexesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takashi Higashino;Yasukata IshiiOrg. Lett.2000/12/28～

PapersReaction of homoallylic alcohols with NaIO4/NaHSO3 reagent - synthesis of alkyl substituted tetrahydrofuran derivativesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yoshio Okimoto;Daisuke Kikuchi;Y.IshiiTetrahedron Lett.41/52, 10223-102272000/12/23～

PapersN-Hydroxyphthalimide-catalyzed radical addition of 1,3-dioxolanes and molecular oxygen to alkenes under ambient conditions: a new route to b-oxycarbonyl compoundsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Kazutaka Hirano;Takahiro Iwahama;Yasutaka IshiiChem. Commun.2000/12/11～

PapersCatalytic radical addition of ketones to alkenes by a metal-dioxygen redox systemIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Iwahama;Y.IshiiChem. Commum.2000/11/22～

PapersAerobic Oxidation of Methylpyridines to Pyridinecarboxylic Acids Catalyzed by N-HydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Akihiro Shibamoto;Yasutaka IshiiOrg. Pro. Res. Dev.2000/11/17～

PapersEfficient oxidation of alcohols to Carbonyl Compounds with Molecular Oxygen Catalyzed by N-hydroxyphthalimide Combined with a Co SpeciesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Iwahama;Yasushi Yoshino;Takashi Keitoku;Yasutaka IshiiJ. Org. Chem.2000/10/9～

PapersAn Efficient Synthesis of Dinitrule Derivatives by the Reaction of Oxime Ester or Acid Anhydrides with Cyanotrimethylsilane Catalyzed by La(OiPr)3In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Akiko Fujii;Yasutaka IshiiJ. Org. Chem.2000/9/22～

PapersThe First Catalytic Sulfoxidation of Saturated Hydrocarbons with SO2/O2 by a Vanadium SpeciesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Katsuhisa MatsunakaJ. Am. Chem. Soc.2000/8/2～

LectureCo-author2000/7/20～

PapersSynthesis of 1,3-oxazolidines from imines and epoxides catalyzed by samarium compoundsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takayuki Nishitani;Hiroyuki Shiraishi;Yasutaka IshiiTetrahedron Lett.2000/4/29～

PapersCatalytic α-hydroxy carbon radical generation and addition. Synthesis of α-hydroxy-γ-lactones from alcohols, α,β-unsaturated esters and dioxygenIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Iwahama;Yasutaka IshiiChem. Commum.2000/3/28～

PapersIridium-catalyzed aziridination of aliphatic aldehyde, aliphatic amine and ethyl diazoacetateIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takashi Kubo;Yasutaka IshiiChem. Commum.2000/3/28～

PapersMeerwein-Ponndorf-Verley-type reductive acetylation of carbonyl compounds to acetates by lanthanide complexes in the presence of isopropenyl acetateIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasuyuki Nakano;Yasutaka IshiiTetrahedron Lett.2000/3/4～Meerwein-Ponndorf-Verley type reductive acetylation of carbonyl compounds to acetates was successfully carried out in the presence of isopropenyl acetate under the influence of a catalytic amount of Ln(OiPr)3 at room temperature. Various carbonyl compounds were converted into the corresponding acetates in fair to good yields.

PapersProduction of Hydrogen Peroxide via Aerobic Oxidation of Alcohols Catalyzed by N-HydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Iwahama;Yasutaka IshiiOrg. Pro. Res. Dev.2000/3/3～

PapersAcetalization of Alkenes Catalyzed by Pd(OAc)2/NPMoV Supported on Activated Carbon under a Dioxygen AtmosphereIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Arata Kishi;Yasutaka IshiiOrg. Lett.2000/2/24～The acetalization of terminal alkenes such as ethyl acrylate and acrylonitrile with alcohols under O2 was efficiently achieved by Pd(OAc)2 supported on activated carbon combined with molybdovanadophosphate (NPMoV). For example, ethyl acrylate was subjected to acetalization with EtOH acidified by CH3SO3H under O2 (1 atm) in the presence of [8 wt%Pd(OAc)2/C] and NPMoV to form ethyl 3,3-diethoxypropionate in quantitative yield.

PapersEpoxidation of alkenes with H2O2 generated in situ from alcohols and molecular oxygen using N-hydroxyphthalimide and hexafluoroacetone as catalystIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Iwahama;Yasutaka IshiiHeterocycles2000/2/22～

総説In refereedAcademic JournalCo-author2000/2/1～

PapersEpoxidation of alkenes using alkyl hydroperoxides generated in situ by catalytic autoxidation of hydrocarbons with dioxygenIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Iwahama;Gou Hatta;Yasutaka IshiiChem. Commum.2000/1/17～

PapersWacker-Type Oxidation of Cyclopentene under Dioxygen Atmosphere Catalyzed by Pd(OAc)2/NPMoV on Activated CarbonIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Arata Kishi;Takashi Higashino;Yasutaka IshiiTetrahedron Lett.2000/1/1～Wacker-type oxidation of cyclopentene to cyclopentanone under dioxygen atmosphere was successfully achieved by the use of Pd(OAc)2 and molybdovanadophosphate supported on activated carbon, [Pd(OAc)2-NPMoV/C], catalyst. Thus, the reaction of cyclopentene under O2 (1 atm) in aqueous acetonitrile acidified by CH3SO3H in the presence of [Pd(OAc)2-NPMoV/C]at 50

C produced cyclopentanone in 85% yield along with a small amount of cyclopentenone (1%).

PapersRegioselective Synthesis of Alkylpyrroles from Imines and Nitroalkenes by Lanthanide CompoundsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Hiroyuki Shiraishi;Takayuki Nishitani;Yasutaka IshiiTetrahedron1999/12/3～A variety of substituted alkylpyrroles were synthesized in regioselective manner by the cyclization of nitroalkenes with imines catalyzed by Sm(Oi-Pr)3 under mild conditions. Tetrahydroindole and carbazole derivatives were also synthesized in fair yields by the use of cyclic nitroalkenes and imines as starting materials. This method provides a novel alternative route for the regioselective synthesis of substituted alkylpyrrole derivatives

PapersOxidative Cleavage of vic-Diols to Aldehyde with Dioxygen Catalyzed by Ru(PPh3)3Cl2 on Active CarvonIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Eiichiro TakezawaOrg. Lett.1999/9/9～

PapersDehomologation OF Aldehydes via Oxidative Cleavage of Silyl Enol Ethers with Aqueous Hydrogen Peroxide Catalyzed by Cetylpyridinium Peroxotungstophosphate(PCWP)under Two-Phase ConditionsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Hiroyo Yamamoto;Yumiko Yamamoto;Takuma SugimotoJ. Org. Chem.1999/8/6～Dehomologation of aldehydes has been first successfully achieved via oxidative cleavage of silyl enol ethers, derived from aldehydes and trimethylchlorosilane (Me3SiCl), using aqueous hydrogen peroxide in the presence of a catalytic amount of peroxotungstophophate (PCWP) under phase-transfer conditions. For instance, the oxidation of 1-[(trimethylsilyl)oxy]-1-octene resulting from octanal and Me3SiCl with 35% H2O2 catalyzed by PCWP in dichloromethane at room temperature afforded the one-carbon shorter aldehyde, heptanal, in 79% yield. A variety of silyl enol ethers were also converted into one-carbon shorter aldehydes in good yields. The oxidation under homogeneous conditions using tert-butyl alcohol gave hydrolysis products such as 2-oxooctanol and octanal. It is of interest that [1-(trimethylsilyl)oxy]-1,10-undecadiene involving an enol moiety and a terminal double bond afforded exclusively 9-decenal in which the enol moiety was selectively oxidized. A plausible reaction path for the oxidative cleavage of silyl enol ethers by the present system has been suggested from the oxidation results of

-[(trimethylsilyl)oxy]styrene.

PapersCatalytic Redical Acetylation of Adamantanes with Biacetyl by a Cobalt Salt Under Armospheric DioxygenIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Susumu Kato;Arata KishiChem. Commum.1999/7/20～The catalytic radical acetylation of adamantanes with biacetyl was successfully achieved by a cobalt salt under O2. Exposure of a mixture of adamantane and biacetyl under O2 in the presence of Co(Oac)2 (0.1 mol%) in acetic acid led to 1-acetyladamantane (47%) and 1,3-diacetyladamantane (20%) as major products along with small amounts of adamantan-1-ol (4%) and adamantan-2-one (3%).

PapersA New Approach for Oxygenation Using Nitric Oxide under the Influence of N-HydroxyphthalimideIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Masahiro EikawaJ. Org. Chem.1999/6/25～An approach for partial oxygenation through a carbocation as an intermediate was successfully developed by using nitric oxide under the influence of N-hydroxyphthalimide. Thus, a variety of benzylic ethers were converted into the corresponding partially oxidized compounds, which are difficult to prepare by conventional methods, in high yields. For example, the reaction of phthalane with NO in the presence of a catalytic amount of NHPI at 60

C gave phthalaldehyde in 80% yield. The reaction was found to proceed through the formation of a hemiacetal, such as 1-hydroxyphthalane. In addition, 1,3-di-tert-butoxymethyl benzene afforded 1,3-benzenedicarbaldehyde in good yield. On the other hand, isochroman was converted into 1,1'-oxodiisochromane under these reaction conditions. The reaction of ethers with NO in the presence of a NHPI catalyst is thought to proceed via the formation of a carbocation as an intermediate. A possible reaction path was suggested.

PapersAcetylcyanation of Aldehydes with Acetone Cyanohydrin and Isopropenyl Acetate by Cp*2Sm(thf)2In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yasushi Nakano;Akiko Fujii;Yumi KawasakiJ. Org. Chem.1999/5/28～

PapersEpoxidation of Alkenes Using Dioxygen in the Presence of An Alcohol Catalyzed By N-Hydroxyphthalimide and Hexafluoroacetone without Any Metal CatalystIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro IwahamaChem. Commum.1999/4/13～

PapersA New Strategy for Alkane Oxidation with O2 using N-Hydroxyphthalimide(NHPI)As a Radical CatalystIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka IshiiCatalysis Surveys from Japan1999/3～

PapersA Remarkable Effect of Quaternary Ammonium Bromide for the N-Hydroxyphthalimide-Catalyzed Aerobic Oxidation of HydrocarbonsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro Iwahama;Katsuhisa MatsunakaTetrahedron Lett.1999/2/8～

PapersCarbonylation of Terminal Alkynes Using a Multicatalytic System, Pb(Ⅱ)Chlorohydroquinone/NPMoV, under Cerbon Monoxide and DioxygenIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yasunori SakuraiTetrahedron Lett.1999/1/25～

PapersSelective Oxidation of Sulfides to Sulfoxides with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide(NHPI)in the Presence of AlcoholsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro IwahamaTetrahedron Lett.1998/11/2～

PapersTrimerization of Aliphatic Aldehydes to1,3-Diol Monoesters Catalyzed by Cp*2Sm(thf)2In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yumi Kawasaki;Daisuke Tashiro;Akira MiyanoTetrahedron Lett.1998/9/17～Aliphatic aldehydes underwent trimerization in the presence of a catalytic amount of Cp*2Sm(thf)2 under ambient conditions to form 1,3-diol monoesters in good yields. For example, the reaction of acetoaldehyde catalyzed by Cp*2Sm(thf)2 gave 4-acetoxy-2-butanol (2a) and 3-acetoxy-1-butanol (3a) in 86% yield.

PapersOxgenation of Alkynes to α, β-Acetylenic Ketones with Dioxygen Catalyzed by N-Hydroxyphthalimide Combined with a Transition MetalIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro Iwahama;Tomoyuki TakaseChem. Commum.1998/9/15～Alkynes were successfully converted into a,b-acetylenic carbonyl compounds through radical-catalyzed autoxidation using N-hydroxyphthalimide (NHPI) combined with a transion metal under mild conditions.

PapersPreparation of Substituted Alkylpyrroles via Samarium-Catalyzed Three-Component Coupling Reaction of Aldehydes, Amines, and NitroalkanesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takayuki Nishitani;Hiroyuki ShiraishiJ. Org. Chem.1998/9/4～

PapersAn Alternative Method for the Selective Bromination of Alkylbenzenes Using NaBrO3/NaHSO3 ReagentIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Daisuke KikuchiJ. Org. Chem.1998/8/21～

PapersSelective Aerobic Oxidation of Primary Alcohols Catalyzed by a Ru(PPh3)3Cl2/Hydroquinone SystemIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Eiichiro Takezawa;Atsushi HanyuTetrahedron Lett.1998/7/30～

PapersDirect Conversion of Cyclohexane into Adipic Acid with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide Combined with Mn(acac)2 and Co(OAc)2In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro IwahamaOrg. Pro. Res. Dev.1998/7/17～

PapersAn Efficient Aerobic Oxidation of Isobutane to t-Butyl Alcohol by N-Hydroxyphthalimide Combined with Co(II)SpeciesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro Iwahama;Susumu KatoBull. Chem. Soc. Jpn.1998/5/15～Highly selective aerobic oxidation of isobutane to t-butyl alcohol was successfully achieved by the use of a radical catalyst, N-hydroxyphthalimide (NHPI), in the presence of Co(II) salt under relatively mild conditions. The oxidation of isobutane by NHPI combined with Co(acac)2 under a pressure of air (10 atm) in benzonitrile at 100

C gave t-butyl alcohol in high yield (84%) along with acetone (13%). The reaction is thought to proceed via hydrogen abstraction from isobutane by the phthalimidooxyl radical (PINO), which seems to be a key active species. The formation of acetone can be explained by a partial b-scission of the t-butoxy radical, generated from the redox decomposition of t-butyl hydroperoxide by cobalt ion. Alkyl-substituted butanes and pentanes were difficult to be oxidized selectively under these conditions because of easy degradation to smaller fragments of the resulting alkoxyl radical intermediates.

PatentsProduction of Nitro CompoundsCo-author1998/3/25～

総説UnrefereedIn-house publicationCo-author1998/3/15～

PapersN-Hydroxyphthalimide(NHPI)-Catalyzed Carboxylation of Polycyclic Alkanes with Carbon Monoxide in the Presence of DioxygenIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro Iwahama;Susumu KatoJ. Org. Chem.1998/1/23～

PapersA Novel Synthesis of 1,3-Diol Diesters by the Reaction of Aldehydes with Oxime Esters Catalyzed by Samarium ComplexIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Daisuke Tashiro;Yumi KawasakiChem. Lett.1998/1/5～

PapersAn Efficient Acylation of tert-Alcohols with Isopropenyl Acetate Mediated by an Oxime Ester and Cp*Sm(thf)2In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yumi Kawasaki;Daisuke TashiroJ. Org. Chem.1997/11/14～

PapersSlective Oxidation of Vinyl Ethers and Silyl Enol Ethers with Hydrogen Peroxide Catalyzed by Peroxotungstophosphate(PCWP)In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Masaya Tsuda;Hiroyo YamamotoJ. Org. Chem.1997/10/17～The oxidation of vinyl and silyl enol ethers with aqueous hydrogen peroxide was first achieved by the use of peroxotungstophosphate (PCWP) as the catalyst. For example, the oxidation of 1-ethoxy-1-octene with a stoichiometric amount of 35% H2O2 in the presence of PCWP (0.5 mol%) in a mixed solvent of methanol and dichloromethane at room temperature gave 1-ethoxy-1-methoxy-2-hydroxyoctane, a synthetic equivalent of 2-hydroxyoctanal, in 70% yield. The oxidation of acyclic silyl enol ethers such as 1-trimethylsilyloxy-1-octene under these conditions gave 1-hydroxy-2-octanone in 72% yield, while the same oxidation in dichloromethane alone resulted in cleavage of the enol double bond to form heptanal in 71% yield. Cyclic silyl enol ethers were converted into the corresponding a-hydroxyketones in 48%-71% yields under similar reaction conditions.

PapersOxidation of Diols and Ethers by NaBrO3/NaHSO3 ReagentIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Daisuke KikuchiBull. Chem. Soc. Jpn.1997/10/15～NaBrO3 combined with NaHSO3 was found to be an excellent oxidizing reagent of alcohols, diols and ethers under mild conditions. A variety of aliphatic and cyclic diols were selectively oxidized with satisfactory yields to the corresponding hydroxy ketones and/or diketones, which are difficult to selectively prepare due to the concomitant formation of cleaved products. For example, 2-hydroxycyclohexanone and 1,2-cyclohexanedione were selectively formed by allowing 1,2-cyclohexanediol to react with NaBrO3/NaHSO3 reagent in a selected solvent. On the other hand, an alkyl ether such as dioctyl ether reacted with NaBrO3/NaHSO3 in water at room temperature to give octyl octanoate in 82% yield. The same oxidation at higher temperature (60

C) produced the a-brominated ester, octyl 2-bromooctanoate, which is considered to be formed through an alkenyl alkyl ether as the intermediate. Treatment of 1-ethoxy-1-heptene with NaBrO3/NaHSO3 afforded ethyl 2-bromoheptanoate and 2-bromoheptanoic acid as the major products.

PapersN-Hydroxyphthalimide(NHPI)-Catalyzed Reaction of Adamantane Under Nitric Oxide AtmosphereIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Masahiro EikawaTetrahedron Lett.1997/10/6～The reaction of adamantane under atmospheric nitric oxide in the presence of N-hydroxyphthalimide (NHPI) which serves as the radical catalyst in a mixed solvent of benzonitrile and acetic acid afforded 1-N-adamantylbenzamide as a principal product along with small amounts of 1-nitroadamantane and 1-hydroxyadamantane. On the other hand, 1-nitroadamantane was obtained in good yield upon treatment of adamantane with NO/O2.

PapersCatalytic Oxidation of Alkylbenzenes with Molecular Oxygen under Normal Pressure and Temperature by N-Hydroxyphthalimide(NHPI)Combined with Co(OAc)2In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro Iwahama;Yoshiaki Hayashi;Yasushi YoshinoJ. Org. Chem.1997/10/3～

PapersSelective Aerobic Oxidation of Isophorone Catalyzed by Molybdovanadophosphate Supported on Carbon(NPMoV/C)In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yasunori Sakurai;Atsushi HanyuTetrahedron Lett.1997/8/27～

PapersCyclotrimerization of Alkynes Using a Multicatalytic System, Pd(II)/Chlorohydroquinone/NPMoV, under DioxygenIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yasunori Sakurai;Takahiro YokotaTetrahedron Lett.1997/6/2～

PapersStereoselective Reduction of β-Hydroxy Ketones with Aldehydes via Tishchenko Reactions Catalyzed by Zirconocene ComplexesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yutaka Nishiyama;Yuji UmekawaJ. Org. Chem.1997/5/16～

PapersDevelopment of New Synthetic Reactions Using Samarium Compounds as CatalystsIn refereedMonographCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yutaka Nishiyama;Yumi Kawasaki;Daisuke Tashiro;Hiroyuki ShiraishiReviews on Heteroatom Chemistry(MYU)1997～

PapersMolybdovanadophosphate(NPMoV)/hydroquinone/O2 system as an efficient reoxidation system in palladium-catalyzed oxidation of alkenesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yutaka Nishiyama;Sinya Fujibayashi;Takahiro YokotaJ. Mol. Cat. A: Chem.1996/12/23～

PapersAldol Type Condensation of Imines Catalyzed by Samarium ComplexesIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yutaka Nishiyama;Yumi Kawasaki;Hiroyuki ShiraishiTetrahedron Lett.1996/9/30～

PapersAn efficient aerobic oxidation of various organic compounds catalyzed by mixed addenda heteropolyoxometalates containing molybdenum and vanadiumIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yutaka Nishiyama;Masatoshi Hamamoto;Koichi Nakayama;Shinya FuzibayashiJ. Mol. Cat. A: Chem.1996/8/10～

PapersSelective Oxidation of Monoterpenes with Hydrogen Peroxide Catalyzed by Peroxotungstophosphate(PCWP)In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka IshiiJ. Org. Chem.1996/8/9～Catalytic epoxidation of monoterpenes with aqueous hydrogen peroxide catalyzed by peroxotungstophosphate (PCWP) under biphase conditions using chloroform as a solvent was examined. A variety of terpenes was oxidized to the corresponding monoepoxides or diepoxides in good yields under mild conditions. For example, limonene (1) was converted into limonene oxide (1a) in which the cyclohexene double bond was selectively epoxidized in almost quantitative yield. The oxidation of g-terpinene (2) with 2.2 equiv of 35% H2O2 took place with high stereoselectivity to give cis-diepoxide 2c. In terpenes bearing electron-withdrawing groups such as neryl acetate (3), geranyl acetate (4), citral (5), and geranyl nitrile (6), the double bonds remote from their substituents were epoxidized in preference to the others. The epoxidation of linalool (9) by the present catalyst-oxidant system produced the cyclic products, hydroxy furan 9a and hydroxy pyran 9b, rather than epoxide. Tert-Butyl alcohol was successfully employed as the solvent by treating a hydrogen peroxide solution of tert-butyl alcohol with MgSO4 prior to use. The regioselectivities in the epoxidation of monoterpenes can be favorably explained by electron densities of the double bonds which were estimated using the CAChe system.

PapersAlkane Oxidetion with Molecular Oxygen Vsing a New Efficient Catalytic System:N-Hydroxyphthalimide (NHPI) Combined with Co(acac)n (n=2or3)In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yutaka Nishiyama;Koichi Nakayama;Takahiro IwahamaJ. Org. Chem.1996/7/12～

PapersHydroxylation of Polycyclic Alkanes with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide (NHPI) Combined with Transition Metal SaltsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Takahiro Iwahama;Susumu KatoTetrahedron Lett.1996/7/8～

PapersAcylation of Alcohols and Amines with Vinyl Acetates Catalyzed by Cp*2Sm(thf)2In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yutaka Nishiyama;Yumi Kawasaki;Mitsuhiro TakenoJ. Org. Chem.1996/3/22～

PapersOxidation of Organic Substrates with Molecular Oxygen Catalyzed by Vanadomolybdophosphate (NPV6Mo6) Combined with N-Hydroxyphthalimide (NHPI)UnrefereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yutaka Nishiyama;Koichi NakayamaTechnology Reports of Kansai University,1996/3/20～

PapersOxidative Esterification of Primary Alcohols by NaBrO3/NaHSO3 Reagent in Aqueous MediumIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Ishii Yasutaka;Yutaka Nishiyama;Osamu Kai;Haruyoshi Masuda;Kiyoshi TakaseChem. Lett.1995/10～

PapersAerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by N-Hydroxyphthalimide (NHPI) CombinedIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Yutaka Nishiyama;Takahiro IwahamaTetrahedron Lett.1995/9/18～

PapersA New Coupling Reaction of Vinyl Esters with Aldehydes Catalyzed by Organosamarium CompoundsIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Shiro Kikuchi;kenichi Morita;Yutaka NishiyamaJ. Org. Chem.1995/8/11～

PapersA Novel Catalysis of N-Hydroxyphthalimide in the Oxidation of Organic Substrates by Molecular OxygenIn refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka Ishii;Kouichi Nakayama;Mitsuhiro Takeno;Hiroyuki Iwahama;Yutaka NishiyamaJ. Org. Chem.1995/6/30～

総説UnrefereedIn-house publicationCo-author1995/3～

PapersA Direct Conversion of vic-Diols into 1,2-Diketones with Agueous Hydrogen Peroxide Catalyzed by Peroxotungstophosphate(PCWP)In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Takahiro Iwahama;Yasutaka IshiiTetrahedron Lett.1995/2/27～

PapersOxidation of Allenes and Alkynes with Hydrogen Peroxide Catalyzed by Cetylpyridinium Peroxotungstophosphate(PCWP)In refereedAcademic JournalCo-authorSAKAGUCHI Satoshi;Yasutaka IshiiJ. Org. Chem.1994/9/23～The oxidation of allenes and alkynes with hydrogen peroxide catalyzed by peroxotungstophosphate (PCWP) was examined. A variety of allenes was first converted into the corresponding a-ethoxy ketones upon treatment with 35 % H2O2 under the influence of PCWP in a mixed solvent consisting of ethanol and dichloromethane. When the reaction was carried out using tert-butyl alcohol as a solvent, approximately a 1:1 regioisomeric mixture of a-hydroxy ketones was obtained along with a small amount of a-tert-butoxy ketone. Oxidation of internal alkynes such as 4-octyne by the PCWP-H2O2 system under phase-transfer conditions using chloroform produced a,b-epoxy ketones in good yields. The same reaction in a mixed solvent of ethanol and chloroform gave a,b-unsaturated ketones rather than a,b-epoxy ketones. The conceivable reaction paths are proposed for the oxidation of allenes and alkynes by the PCWP-H2O2 system

Research Activities Overseas

Kansai University's Overseas Research Program(long term)Sep. 10,2006-Sep. 10,2007USA USC

Participation in International Conferences

1995 International Chemical Congress of Pacific Basin Societies Dec.17,1995-Dec. 22,1995
2000 International Chemical Congress of Pacific Basin Societies Dec.14,2000-Dec. 19,2000
37th National Organic Chemistry Symposium Jun.10,2001-Jun. 14,2001
11th IUPAC Symposium on Organometallic Chemistry directed towords Organic Symthesis Jul.22,2001-Jul. 26,2001
14th International Conference on Organic Synthesis (ICOS-14) Jul.14,2002-Jul. 18,2002
13th International Symposium on Homogeneous Catalysis (13th ISHC) Sep.2,2002-Sep. 7,2002
2003 Gordon Research Conferences on Hydrocarbon Resources Jan.12,2003-Jan. 16,2003
13th European Symposium on Organic Chemistry Sep.9,2003-Sep. 17,2003
14th International Symposium on Homogeneous Catalysis (14th ISHC) Jul.5,2004-Jul. 9,2004
International Symposium on Catalysis and fine chemicals 2004 (C&FC2004) Dec.12,2004-Dec. 15,2004
14th European Symposium on Organic Chemistry (ESOC-14) Jul.3,2005-Jul. 9,2005
Balticum Organicum Syntheticum (BOS2006 Tallin) Jun.24,2006-Jun. 30,2006
ACS National Meeting 2007 Fall Aug.20,2007-Aug. 23,2007
16th International Symposium on Homogeneous Catalysis (16th ISHC) Jul.6,2008-Jul. 11,2008
15th IUPAC Symposium on Organometallic Chemistry directed towords Organic Symthesis Jul.26,2009-Jul. 30,2009
International Symposium on Catalysis and Fine Chemicals (C&FC 2009) Dec.13,2009-Dec. 17,2009
Univerisity of Southern California Mar.9,2008-Mar. 18,2008
Univerisity of Southern California Mar.11,2009-Mar. 16,2009
2010 International Chemical Congress of Pacific Basin Societies Dec.15,2010-Dec. 20,2010
Univerisity of Southern California Feb.23,2011-Feb. 28,2011
16th IUPAC Symposium on Organometallic Chemistry directed towords Organic Symthesis Jul.23,2011-Jul. 28,2011
Univerisity of Southern California Feb.23,2012-Feb. 29,2012
ACS National Meeting 2012 Fall Aug.16,2012-Aug. 25,2012
18th European Symposium on Organic Chemistry Jul.6,2013-Jul. 15,2013
15th Tetrahedron Symposium- Asian Edition Oct.28,2014-Nov. 2,2014
17th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis Jul.12,2015-Jul. 18,2015
9th Asian-European Symposium on Metal-Mediated Efficient Organic Synthesis Sep.4,2016-Sep. 8,2016
Aug.17,2018-Aug. 24,2018